文献类型： 外文期刊

作者： Zheng Yun-Yun ¹ ; Huang Rui-Min ¹ ; Wei Hang ¹ ; Huang Biao ¹ ; Su De-Sen ¹ ; Fu Ban-Wei ¹ ;

作者机构： 1.Fujian Acad Agr Sci, Inst Qual Stand & Testing Technol Res Agroprod, Fuzhou 350003, Fujian, Peoples R China

2.Fujian Acad Agr Sci, Inst Subtrop Agr Res, Zhangzhou 3630005, Fujian, Peoples R China

关键词： thiophenedicarboxylate; lanthanide; crystal; synthesis

期刊名称：CHINESE JOURNAL OF INORGANIC CHEMISTRY （ 影响因子：0.834； 五年影响因子：0.604 ）

ISSN： 1001-4861

年卷期： 2018 年 34 卷 4 期

页码：

收录情况： SCI

摘要： Three lanthanide-based coordination polymers, namely {[La(OH)(SO4)]}(n) (1), {[La-2(TDC)(2)(SUC)]}(n) (2) and {[Gd-2(TDC)(2)(ox) (H2O)(4)]center dot 2H(2)O}(n) (3) (H2TDC=2,5-thiophenedi-carboxylic acid, SUC=succinate, ox=oxalate), were synthesized through hydrothermal reaction of H2TDC and Ln(NO3)(3) (Ln=La, Gd). Investigation on the crystal structure indicates that complex 2 and 3 feature 3D frameworks. Crystal data are orthorhombic, space group Pbca, a=1.372 8(4) nm, b=0.704 0(2) nm, c=2.136 2(6) nm, Z=8 for 2; and monoclinic, space group, C2/c, a=1.934 3(4) nm, b=0.990 5(2) nm, c=1.252 8(3) nm, beta=107.463(4)degrees, Z=4 for 3. CCDC: 1818984, 2; 1818985, 3.