Electrochemical sensor for the determination of dimetridazole using a 3D Cu2O/ErGO-modified electrode
文献类型: 外文期刊
作者: Ma, Xionghui 1 ; Li, Jianping 3 ; Luo, Jinhui 1 ; Liu, Chunhua 1 ; Li, Shuhuai 1 ;
作者机构: 1.Chinese Acad Trop Agr Sci, Anal & Test Ctr, Haikou 571101, Hainan, Peoples R China
2.Minist Agr, Lab Qual & Safety Risk Assessment Trop Prod Haiko, Haikou 571101, Hainan, Peoples R China
3.Guilin Univ Technol, Coll Chem & Bioengn, Guangxi Key Lab Electrochem & Magnetochem Funct M, Guilin 541004, Peoples R China
期刊名称:ANALYTICAL METHODS ( 影响因子:2.896; 五年影响因子:2.716 )
ISSN: 1759-9660
年卷期: 2018 年 10 卷 27 期
页码:
收录情况: SCI
摘要: A three-dimensional Cu2O/electrochemically reduced graphene (ErGO)-modified electrode was developed for the determination of dimetridazole. Cu2O/GO was initially prepared using a modified solvothermal method, and the 3D structure was constructed by electrodepositing a Cu2O/GO dispersion on a glassy carbon electrode in the presence of lithium perchlorate. The enhanced electrocatalytic reduction of dimetridazole was confirmed, and the electrochemical reduction reaction was found to be a typical adsorption-controlled process. Our results revealed that the response to dimetridazole was linear in the concentration range of 30-150 nmol L-1 and the detection limit was 3.64 nmol L-1. The prepared electrode was also employed to detect dimetridazole in an egg sample, thereby indicating its potential practical application.
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