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Re-evaluation of stability and toxicity of silver sulfide nanoparticle in environmental water: Oxidative dissolution by manganese oxide

文献类型： 外文期刊

作者： Shi, En 1 ; Xu, Zhenlan 2 ; Zhang, Xiaoxia 1 ; Yang, Xuezhi 3 ; Liu, Qian 3 ; Zhang, Hangjun 4 ; Wimmer, Andreas 5 ; Li, 1 ;

作者机构： 1.Zhejiang Sci Tech Univ, Sch Sci, Dept Chem, Hangzhou 310018, Zhejiang, Peoples R China

2.Zhejiang Acad Agr Sci, Inst Qual & Stand Agroprod, Hangzhou 310021, Zhejiang, Peoples R China

3.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China

4.Hangzhou Normal Univ, Coll Life & Environm Sci, Hangzhou 310036, Zhejiang, Peoples R China

5.Tech Univ Munich, Dept Chem, Div Analyt Chem, D-85748 Garching, Germany

关键词： Silver sulfide nanoparticle; Manganese oxide; Stability; Oxidative dissolution; Acute toxicity

期刊名称：ENVIRONMENTAL POLLUTION （ 影响因子：8.071； 五年影响因子：8.35 ）

ISSN： 0269-7491

年卷期： 2018 年 243 卷

页码：

收录情况： SCI

摘要： Stability of silver sulfide nanoparticle (Ag2S-NP) in the environment has recently drawn considerable attention since it is associated with environmental risk. Although the overestimated stability of Ag2S-NP in aqueous solution has already been recognized, studies on transformation of Ag2S-NP in environmental water are still very scarce. Here we reported that Ag2S-NP could undergo dissolution by manganese(IV) oxide (MnO2), an important naturally occurring oxidant in the environment, even in environmental water, although the dissolved silver would probably be adsorbed onto the particles (>0.45 mu m) in environmental water, mitigating the measurable levels of dissolved silver. The extent and rate of Ag2S-NP dissolution rose with the increasing concentration of MnO2. In addition, environmental factors including natural organic matter, inorganic salts and organic acids could accelerate the Ag2S-NP dissolution by MnO2, wherein an increase in dissolution extent was also observed. We further documented that Ag2S-NP dissolution by MnO2 was highly dependent on O-2 and it was an oxidative dissolution, with the production of SO4.2- Finally, dissolution of Ag2S-NP by MnO2 affected zebra fish (Danio rerio) embryo viability, showing significant reduction in embryo survival and hatching rates, compared to embryos exposed to Ag2S-NP, MnO2 or dissolved manganese alone. These findings would further shed light on the stability of Ag2S-NP in the natural environment - essential for comprehensive nano risk assessment. (C) 2018 Elsevier Ltd. All rights reserved.

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