A simple and sensitive non-chromatographic method for quantification of four arsenic species in rice by hydride generation - atomic fluorescence spectrometry
文献类型： 外文期刊
作者： Wang, Ya 1 ; Li, Youqing 1 ; Lv, Kang 1 ; Chen, Xiaolong 1 ; Yu, Xiangyang 1 ;
作者机构： 1.Minist Sci & Technol, State Key Lab Cultivat Base, Jiangsu Key Lab Food Qual & Safety, Nanjing 210014, Jiangsu, Peoples R China
2.Jiangsu Acad Agr Sci, Inst Food Safety & Nutr, Nanjing 210014, Jiangsu, Peoples R China
3.Jiangsu Acad Agr Sci, I
关键词： Arsenic speciation; Atomic fluorescence spectrometry; Hydride generation; Non-chromatographic; Rice
期刊名称：SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY （ 影响因子：3.752； 五年影响因子：3.375 ）
ISSN： 0584-8547
年卷期： 2018 年 149 卷
页码：
收录情况： SCI
摘要： Herein, a simple, sensitive and effective non-chromatographic analytical method was developed for speciation analysis of four target arsenic (As) species in rice samples. The hydride generation conditions and sample pretreatment techniques were optimized for the determination of arsenite [As(III)], arsenate [As(V)], monomethylarsonic acid [MMA(V)] and dimethylarsinic acid [DMA(V)]. For optimum results, hydrochloric acid/sodium citrate buffer (1.6 mol L-1 sodium citrate; pH 4.8) was used for the carrier solution and 0.06 mol L-1 citric acid for sample acidification. The concentrations of the four As species were determined by hydride generation-atomic fluorescence spectrometry using a series of linear independent equations corresponding to four different sample pretreatment procedures. The limits of detection of the method were 0.21, 0.52, 0.65 and 0.9 mu g kg(-1) for As(III), As(V), MMA(V) and DMA(V), respectively. Extraction efficiencies (96-104%) and recoveries of As species in rice (95-100%) were always good, and interconversion among the four As species in the extract did not occur.
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