您好，欢迎访问贵州省农业科学院 机构知识库！
贵州省农业科学院机构知识库

全部

  • 全部
  • 标题
  • 学者
  • 机构
  • 关键词

A sensitive method for quantification of the insecticide spinetoram in 13 different plant- and animal-type foods by ultra-high performance liquid chromatography-tandem mass spectrometry

文献类型： 外文期刊

作者： Zhang, Ying 1 ; Wei, Jin 1 ; Long, Jiahuang 1 ; Zhu, Feng 1 ; Liao, Guohui 1 ; Duan, Tingting 1 ; Chen, Caijun 1 ;

作者机构： 1.Guizhou Acad Agr Sci, Inst Plant Protect, Guiyang, Guizhou, Peoples R China

关键词： Spinetoram; UHPLC-MS/MS; plant-type foods; animal- type foods; residue

期刊名称：INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY （ 影响因子：2.826； 五年影响因子：2.215 ）

ISSN： 0306-7319

年卷期： 2019 年 99 卷 2 期

页码：

收录情况： SCI

摘要： We developed a simple, sensitive and rapid analytical method for simultaneous quantification of spinetoram (XDE-175-L and XDE-175-J) residue in foods originating from plants (cucumber, cabbage, eggplant, pepper, bayberry, mango, rice, wheat, and codonopsis) or animals (eggs, milk, pork, and chicken). The method was validated by ultra-high performance liquid chromatography coupled to tandem mass spectrometry, run in the positive-ion mode with selected reaction monitoring. Briefly, the samples were extracted with acetonitrile and purified via dispersive solid-phase extraction with octadecylsilane, primary secondary amine, or graphitized carbon black, used either singly or in combination. The method provides good linearity (R-2 >= 0.9956) and outstanding performance (trueness and recovery percentages 80.1-111.3%; intra-day/inter-day precision of 1.2-9.7% and 3.9-12.9%). For all food matrices, the limit of quantification was 0.125 mu g kg(-1) for XDE-175-L and 0.375 mu g kg(-1) for XDE-175-J. We also validated the applicability of the method using 130 samples obtained from commercial sources, which revealed trace amounts of spinetoram in 28 of those samples. The data indicated that the method yields reproducible results and is sufficiently sensitive for the detecting trace amounts of spinetoram in plant- and animal-type foods.

  • 相关文献
作者其他论文 更多>>
置顶
购物车
反馈

© 京ICP备09089781号-29 主办单位：贵州省农业科学院

学术资源： 中国农业科学院 农业专业知识服务系统 农科联盟资源共建共享平台 中国农业科技文献与信息服务平台 中国农业期刊集成服务平台