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Copolymerization of 4,4 '-divinyl benzoyl peroxide with methyl methacylate and grafting of butyl acrylates onto the copolymers

文献类型: 外文期刊

作者: Li, Z 1 ; Du, QG 2 ; Shi, XZ 2 ; Tao, FG 2 ; Wang, QR 2 ; Swift, G 2 ; Wu, SG 2 ;

作者机构: 1.Fudan Univ, Dept Macromol Sci, Mol Engn Polymers Main Lab, Shanghai 200433, Peoples R China

2.Fudan Univ, Dept Macromol Sci, Mol Engn Polymers Main Lab, Shanghai 200433, Peoples R China; Rohm & Haas Co, Spring House, PA 19477 USA

关键词: End group;Macromonomer;Polystyrene

期刊名称:MACROMOLECULAR RAPID COMMUNICATIONS ( 影响因子:5.734; 五年影响因子:4.905 )

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年卷期:

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收录情况: SCI

摘要: A peroxide monomer, 4,4'-divinyl benzoyl peroxide (DVBPO), was synthesized. Bulk copolymerization of DVBPO with methyl methacrylate (MMA) was initiated by di(2-ethyl hexyl)peroxy carbonate (EHP). DSC curves and the appearance of crosslinking of the product showed that DVBPO can copolymerize with MMA. The grafting copolymerization of butyl acrylate (BA) onto the copolymer was performed. The grafting efficiency (GE), determined by Soxhlet extraction, was high. [References: 17]

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