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Suspecting screening "known unknown" pesticides and transformation products in soil at pesticide manufacturing sites

文献类型： 外文期刊

作者： Tao, Yufeng 1 ; Liu, Jing 1 ; Xu, Yiwen 1 ; Liu, Hang 1 ; Yang, Guiling 2 ; He, Yan 1 ; Xu, Jianming 1 ; Lu, Zhijiang 3 ;

作者机构： 1.Zhejiang Univ, Coll Environm & Resource Sci, Inst Soil & Water Resources & Environm Sci, Zhejiang Prov Key Lab Agr Resources & Environm, Hangzhou 310058, Zhejiang, Peoples R China

2.Zhejiang Acad Agr Sci, Inst Qual & Stand Agroprod, State Key Lab Qual & Safety Agroprod, Key Lab Pesticide Residue Detect,Minist Agr, Hangzhou 310021, Zhejiang, Peoples R China

3.Wayne State Univ, Dept Environm Sci & Geol, Detroit, MI 48201 USA

关键词： HR-MS; Occurrence; Brownfield; Risk assessment; Site investigation

期刊名称：SCIENCE OF THE TOTAL ENVIRONMENT （ 影响因子：10.753； 五年影响因子：10.237 ）

ISSN： 0048-9697

年卷期： 2022 年 808 卷

页码：

收录情况： SCI

摘要： The occurrence and risks of pesticides and their transformation products in soil at the manufacturing sites are "known unknowns." In this study, pesticides and their transformation products were screened in soil at 6 pesticide manufacturing sites across China using liquid and gas chromatography coupled with quadrupole time-of-flight mass spectrometry. The screening strategy can correctly identify 75% of 209 pesticides spiked at 50 ng g(-1). A total of 212 pesticides were identified; 23.1% of pesticides detected were above 200 ng g(-1) , and the maximum concentration was 1.5 x 10(5) ng g(-1). The risk quotients of 20% pesticides were greater than 1, and the maximum risk quotient of imidacloprid reached 6.3 x 10(4). The most recent site showed a larger number of pesticides with higher diversity, whereas older sites were dominated by organochlorine insecticides.The extended screen identified 163 transformation products with concentrations up to 6.6 x 10(4) ng g(-1). Half of the transformation products had higher concentrations than their parent compounds, and metabolic ratios up to 371 were observed. The results of this study validate the prevalence of pesticides and their transformation products in soil at pesticide manufacturing sites. The results also highlight the importance of comprehensive screening at industrial sites and call for improved management and regulation of pesticide manufacturing, particularly for in-service facilities.

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