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Impact of Composite Preservation System on the Vulcanization Performance of Natural Rubber Latex

文献类型: 外文期刊

作者: Zhao, Li-Guang 1 ; Liu, Yi-Qun 1 ; Chen, Min-Min 3 ; Li, Jian-Wei 2 ; Dai, Tuo 2 ; Ye, Shao-Xiang 2 ; Liu, Wei-Qiang 2 ; Zhao, Tao 2 ; Gui, Hong-Xing 2 ; Xin, Zhen-Xiang 1 ;

作者机构: 1.Qingdao Univ Sci & Technol, Coll Polymer Sci & Engn, Qingdao 266042, Peoples R China

2.Chinese Acad Trop Agr Sci, Rubber Res Inst, Hainan Nat Rubber Technol Innovat Ctr, Haikou 571101, Peoples R China

3.Sanya Inst Qual & Technol Supervis Hainan Prov, Sanya 572099, Peoples R China

关键词: Natural rubber latex; Preservation system; Thioacetamide derivative; Vulcanization; Mechanical properties

期刊名称:CHINESE JOURNAL OF POLYMER SCIENCE ( 影响因子:4.0; 五年影响因子:3.5 )

ISSN: 0256-7679

年卷期: 2025 年 43 卷 9 期

页码:

收录情况: SCI

摘要: The thioacetamide derivative (TD)-composite preservation system (TDCPS) exhibits superior preservation effects on natural rubber latex (NRL) and significantly enhances its vulcanization efficiency and mechanical properties. This study primarily investigated the principal chemical groups and mechanism of action of TDCPS in promoting NRL vulcanization through a comparative analysis. The results indicated that the key functional groups (thioamide and pyridine) in TDCPS synergistically accelerated crosslinking, reducing the vulcanization time by 41.18% compared to the high-ammonia (HA) preservation system. At an optimal TDCPS dosage of 5 mmolL-1, vulcanized films achieved a tensile strength of 34.18 MPa, with a sulfur content of 1.5 phr further improving the strength by 42.26%. TD outperformed the conventional accelerators 2-imidazolidinethione (ETU) and 3-hydroxypyridine (3-Hp) in promoting the crosslinking density and mechanical performance while eliminating ammonia-related environmental risks. This eco-friendly system demonstrates the industrial potential for sustainable rubber production.

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