文献类型： 外文期刊
作者： Qian, Cheng 1 ; Ma, Jie 2 ; Wu, Qiong 3 ;
作者机构： 1.Northwest Univ, Coll Urban & Environm Sci, Shaanxi Key Lab Earth Surface Syst & Environm Carr, Xian 710127, Peoples R China
2.Northwest Univ, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Xian 710127, Peoples R China
3.Chinese Acad Trop Agr Sci, Anal & Testing Ctr, Haikou 571101, Peoples R China
关键词： Microwave-induced plasma; Methomyl; Degradation; Plackett-Burman design; Mechanism
期刊名称：ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH （ 影响因子：5.8； 五年影响因子：5.4 ）
ISSN： 0944-1344
年卷期： 2023 年 30 卷 23 期
页码：
收录情况： SCI
摘要： As a typical carbamate pesticide, methomyl was once widely used in agriculture for its excellent broad-spectrum insecticidal effect. However, due to its high toxicity, long half-life, and difficult degradation properties, it poses a serious challenge to water environment pollution. In this study, an electrode-free discharge microwave-induced plasma technology was used to rapidly and efficiently degrade methomyl in aqueous solution. In this experiment, the statistical design of experiments (DOE) was adopted to optimize the plasma degradation parameters. Under the optimized parameters (P = 140 W, D = 0 mm, R = 0.5 L/min), 78.4% removal of 50 mg/L of methomyl was achieved after 8 min. The optical emission spectrometry and free radical detection experiments showed that the active substances generated by the collision reaction between plasma and water molecules occurring at the gas-liquid interface were the key factors to exert the degradation effect. The degradation rate of methomyl decreased by 73.2% after the addition of tert-butanol (OH burster), while it decreased by only about 12.0% after the addition of peroxidase. These implied that center dot OH was largely responsible for methomyl degradation. In addition, based on the detected intermediates, possible degradation mechanisms and pathways were analyzed.
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