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Phosphorus-Enhanced and Calcium-Retarded Transport of Ferrihydrite Colloid: Mechanism of Electrostatic Potential Changes Regulated via Adsorption Speciation

文献类型： 外文期刊

作者： Ma, Jie 4 ; Li, Jinbo 1 ; Weng, Liping 4 ; Ouyang, Xiaoxue 1 ; Chen, Yali 4 ; Li, Yongtao 1 ;

作者机构： 1.Minist Agr & Rural Affairs, Agroenvironm Protect Inst, Tianjin 300191, Peoples R China

2.Beijing Forestry Univ, Sch Grassland Sci, Beijing 100083, Peoples R China

3.Tianjin Acad Agr Sci, Inst Agr Prod Qual Safety & Nutr, Tianjin 300381, Peoples R China

4.Minist Agr & Rural Affairs, Agroenvironm Protect Inst, Key Lab Environm Factors Control Agroprod Qual Saf, Tianjin 300191, Peoples R China

5.South China Agr Univ, Coll Nat Resources & Environm, Guangzhou 510642, Peoples R China

6.Wageningen Univ, Dept Soil Qual, NL-6700 Wageningen, Netherlands

关键词： ferrihydrite colloids; phosphorus; calcium; transport; CD-MUSIC; DFT calculation

期刊名称：ENVIRONMENTAL SCIENCE & TECHNOLOGY （ 影响因子：11.4； 五年影响因子：12.0 ）

ISSN： 0013-936X

年卷期： 2023 年 57 卷 10 期

页码：

收录情况： SCI

摘要： The transport of ferrihydrite colloid (FHC) through porous media is influenced by anions (e.g., PO43-) and cations (e.g., Ca2+) in the aqueous environment. This study investigated the cotransport of FHC with P and P/Ca in saturated sand columns. The results showed that P adsorption enhanced FHC transport, whereas Ca loaded onto P-FHC retarded FHC transport. Phosphate adsorption provided a negative potential on the FHC, while Ca added to P-FHC led to electrostatic screening, compression of the electric double layer, and formation of Ca5(PO4)3OH followed by heteroaggregation at pH >= 6.0. The monodentate and bidentate P surface complexes coexisted, and Ca mainly formed a ternary complex with bidentate P (-(FeO)2PO2Ca). The unprotonation bidentate P at the Stern 1-plane had a considerable negative potential at the Van der Waals molecular surface. Extending the potential effect to the outer layer of FHC, the potential at the Stern 2-plane and zeta potential exhibited a corresponding change, resulting in a change in FHC mobility, which was validated by comparison of experimental results, DFT calculations, and CD-MUSIC models. Our results highlighted the influence of P and Ca on FHC transport and elucidated their interaction mechanisms based on quantum chemistry and colloidal chemical interface reactions.

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