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Authentication of edible herbal materials and food products using mass spectrometry based metabolites and inorganic constituents

文献类型： 外文期刊

作者： Wadood, Syed Abdul 1 ; Nie, Jing 1 ; Song, Yan 5 ; Li, Chunlin 1 ; Rogers, Karyne M. 3 ; Khan, Wahab Ali 6 ; Khan, Abbas 6 ; Xiao, Jianbo 4 ; Liu, Hongyan 5 ; Yuan, Yuwei 1 ;

作者机构： 1.Zhejiang Acad Agr Sci, State Key Lab Managing Biot & Chem Threats Qual &, Hangzhou 310021, Peoples R China

2.Zhejiang Acad Agr Sci, Inst Agroprod Safety & Nutr, Hangzhou 310021, Peoples R China

3.Minist Agr & Rural Affairs China, Key Lab Informat Traceabil Agr Prod, Hangzhou 310021, Peoples R China

4.Univ Vigo, Fac Food Sci & Technol, Dept Analyt Chem & Food Sci, Vigo 36310, Spain

5.Chinese Acad Agr Sci, Inst Urban Agr, Res Ctr Plants & Human Hlth, Chengdu 610213, Peoples R China

6.Univ Home Econ Lahore, Dept Food Sci, Lahore, Pakistan

7.GNS Sci, Natl Isotope Ctr, 30 Gracefield Rd, Lower Hutt 5040, New Zealand

关键词： Medicinal food homologous products; Geographical authentication; Adulteration; Metabolites; Stable isotopes; Food fraud

期刊名称：FOOD CHEMISTRY （ 影响因子：9.8； 五年影响因子：9.7 ）

ISSN： 0308-8146

年卷期： 2025 年 463 卷

页码：

收录情况： SCI

摘要： Medicinal food homologous (MFH) substances not only provide nutrition but also serve as a traditional means to overcome many health issues. Authentication of these products verifies their efficacity and assures consumers of a genuine product. In this review paper, we focus the determination of MFH authenticity including geographical identification and adulteration detection using mass spectrometry (liquid and gas chromatography) based metabolites and inorganic constituents (muti-elements and stable isotopes). The application of these techniques to determine product identification characteristics combined with chemometrics are discussed, along with the limitations of these techniques. Multi-elements, stable isotopes, and metabolite analysis are shown to provide an effective combination of techniques to resolve the origin of various MFH products. Most organic compounds from MFH products are identified using chromatographic separation techniques (HPLC, GC) combined with different detection methods. Chemometric analysis of organic and inorganic fingerprints offers a robust method to detect and classify mislabeled and suspected fraudulent samples of different MFH products.

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