Electro-adsorption of Sr(II) from aqueous solution by activated carbon cloth/nickel hexacyanoferrate composite electrode through capacitive deionization
文献类型: 外文期刊
作者: Liu, Xiaojing 1 ; Wu, Jinling 2 ; Wang, Jianlong 2 ;
作者机构: 1.Jiangsu Acad Agr Sci, Inst Agr Resource & Environm Sci, Nanjing 210014, Peoples R China
2.Tsinghua Univ, Lab Environm Technol, INET, Beijing 100084, Peoples R China
3.Tsinghua Univ, Beijing Key Lab Radioact Waste Treatment, Beijing 100084, Peoples R China
4.Tsinghua Univ, INET, Energy Sci Bldg, Beijing 100084, Peoples R China
关键词: Capacitive deionization; ACC; NiHCF composite; Sr2+removal; Adsorption
期刊名称:JOURNAL OF CLEANER PRODUCTION ( 影响因子:11.1; 五年影响因子:11.0 )
ISSN: 0959-6526
年卷期: 2022 年 380 卷
页码:
收录情况: SCI
摘要: The activated carbon cloth/nickel hexacyanoferrate (ACC/NiHCF) electrode was successfully synthesized by a co-precipitation method, and the performance was comprehensively evaluated as CDI electrode materials for Sr2+ removal. The as-prepared ACC/NiHCF electrode had the mesoporous and the coordination framework structure, which provided convenient transport channels for ions or electrons. As a result, the ACC/NiHCF electrode exhibited the high Sr2+ removal efficiency. The maximum removal efficiency was 77.20% at 0.6 V in 5 mg L-1 SrCl2 solution, much higher that of pristine ACC. The isotherm models and mass transfer models sug-gested that the adsorption process of Sr2+ onto ACC/NiHCF was mainly through the multi-layer adsorption, and adsorption onto the active sites was the main rate-limiting step. In addition, the comprehensive characterizations elaborated the mechanism involved physic-chemical adsorption and electrostatic adsorption. Above all, ACC/ NiHCF is an efficient electrode for Sr2+ removal. This study provided new insight into the fabrication of high -efficiency composite electrode materials for Sr2+ removal by CDI.
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