文献类型： 外文期刊

作者： Wang, Ling-Yun ¹ ; Ran, Xue-Guang ¹ ; Cao, De-Rong ¹ ; Hao, Jie ² ;

作者机构： 1.S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China

2.Guangdong Acad Agr Sci, Inst Anim Sci, Guangzhou 510640, Peoples R China

关键词： Reduced Schiff base;D;L-Selenomethionine;Metal complexes;Single-crystal X-ray structure

期刊名称：JOURNAL OF COORDINATION CHEMISTRY （ 影响因子：1.751； 五年影响因子：1.462 ）

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收录情况： SCI

摘要： New zinc(II) and copper(II) complexes with a reduced Schiff-base ligand derived from D,L-selenomethionine and salicylaldehyde have been synthesized and characterized by elemental analysis, magnetic susceptibility, IR, and NMR measurements. The single-crystal X-ray structure of the Cu(II) complex reveals that this complex is a carboxylate-bridged dimer of dinuclear copper(II) subunits and all metal centers are five-coordinate with O4N donor sets in distorted square-pyramidal geometries. The Cu(II) complex consists of a 1-D coordination polymer.