Preparation and characterization of a novel fluoro-silicone acrylate copolymer by semi-continuous emulsion polymerization
文献类型： 外文期刊
作者： Xu, Lin 1 ; Xu, Lei 2 ; Dai, Wei-shuai 1 ; Tsuboi, Taiju 3 ; Xie, Hong-de 1 ;
作者机构： 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215021, Peoples R China
2.Jiangsu Acad Agr Sci, Nanjing 210014, Jiangsu, Peoples R China
3.Nanjing Univ Technol, Inst Adv Mat, Nanjing 210009, Jiangsu, Peoples R China
关键词： Fluoro-silicone copolymer;Nano-particle;Emulsion polymerization;Hydrophobic
期刊名称：JOURNAL OF FLUORINE CHEMISTRY （ 影响因子：2.05； 五年影响因子：2.019 ）
ISSN：
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收录情况： SCI
摘要： A novel fluoro-silicone acrylate (FSA) copolymer latex was synthesized with 2-acrylamido-2-methyl-propanesulfonic acid (AMPS), which served as a polymerizable emulsifier by semi-continuous emulsion polymerization. Methyl methacrylate (MMA), butyl acrylate (BA) and 1,3,5-trimethyltris (3,3,3-trifluoropyropyl) cyclotrisiloxane (D3F) were served as co-monomers while vinyltriethoxysilane (VTES) was used as a cross-linking agent. The structure and surface morphologies of the copolymer were characterized by FT-IR, 'H NMR, TEM, TGA and DSC. The influences of AMPS, D3F and VTES on the copolymer's properties of appearance, conversion rate, gel rate and solid content were discussed. The analytical results indicated that the FSA copolymer latex had a narrow particle size distribution around 100 nm with high temperature stability. The copolymer latex shows excellent water repellency with the contact angles of cotton and silk textile of 125.8° and 120.7°, respectively.
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