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Zinc coordination polymers with rigid dicarboxylates and semirigid 3,5-bis(imidazole-1-yl) pyridine: syntheses, structural topologies, and luminescent properties

文献类型： 外文期刊

作者： Xu, Jiakun 1 ; Sun, Xiaochun 2 ; Ju, Caixia 1 ; Sheng, Jun 1 ; Wang, Fang 1 ; Sun, Mi 1 ;

作者机构： 1.Chinese Acad Fishery Sci, Yellow Sea Fisheries Res Inst, Qingdao, Peoples R China

2.Natl Oceanog Ctr, Qingdao, Peoples R China

3.Shanghai Ocean Univ, Coll Food Sci & Technol, Shanghai, Peoples R China

关键词： Zinc(II) coordination polymers;Crystal structure;Luminescence

期刊名称：JOURNAL OF COORDINATION CHEMISTRY （ 影响因子：1.751； 五年影响因子：1.462 ）

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收录情况： SCI

摘要： Two metal coordination polymers, {[Zn(bpdc)(bip)]-2H_2O}_n (1) and [Zn(tdc)(bip)] (2) [H_2bpdc = biphenyl-4,4'-dicarboxylate, H_2tdc = thiophene-2,5-dicarboxylate, bip = 3,5-bis(imidazole-1-yl)pyridine], have been synthesized and characterized by IR, elemental analysis, XRD, and X-ray single-crystal diffraction. In 1, bpdc and bip link Zn(II) ions into a corrugated 2D layer. The corrugated 2D layers polycatenate each other, yielding a 2D—>3D polycatenation net. In 2, dinuclear Zn(II) units are formed by bip and further connected by tdc to construct a 2D 3-connected framework. The luminescent properties of 1 and 2 are investigated in the solid state at room temperature.

  • 相关文献

[1]Construction of cadmium(II) and zinc(II) coordination frameworks based on 3,5-bis(benzoimidazo-1-ly)pyridine and carboxylate acids: Synthesis, crystal structures and photoluminescent properties. Xu, Jiakun,Wang, Shuaiyu,Sun, Mi,Xu, Jiakun,Yan, Xingchen,Sun, Xiaochun,Yan, Xingchen. 2013

[2]Synthesis, Crystal Structures and Luminescent Properties of pH-Dependent Zn (II) Coordination Polymers. Xu, Jiakun,Sun, Mi,Xu, Jiakun,Fan, Yuhua,Bi, Caifeng,Sun, Xiaochun. 2012

[3]Coordination Frameworks based on 3,5-Bis(imidazole-1-yl)pyridine and Aromatic Dicarboxylate Ligands: Synthesis, Crystal Structures, and Photoluminescent Properties. Xu, Jiakun,Sun, Mi,Xu, Jiakun,Yan, Xincheng,Bi, Caifeng,Sun, Xiaochun,Yang, Lirong.

[4]Crystal structures and theoretical calculations of two peculiar compounds derived from 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one. Yan, Xingchen,Wu, Xiaojing,Xu, Jiakun,Fan, Yuhua,Bi, Caifeng,Zhang, Xia,Zhang, Zhongyu,Yan, Xingchen,Xu, Jiakun. 2014

[5]Hydrothermal synthesis of five new coordination polymers based on benzophenone-2, 4'-dicarboxylic acid and N-donor spacers. Xu, Jiakun,Fan, Yuhua,Bi, Caifeng,Xu, Jiakun,Sun, Mi,Sun, Xiaochun.

[6]Crystal structure of 2-aminobenzothiazolinium nitrate and theoretical study of the amino-imino tautomerism of 2-aminobenzothiazole. Yan, Xingchen,Wu, Xiaojing,Xu, Jiakun,Fan, Yuhua,Bi, Caifeng,Zhang, Xia,Zhang, Zhongyu,Yan, Xingchen,Xu, Jiakun.

[7]Crystal structure of cyclic nucleotide-binding-like protein from Brucella abortus. He, Zheng,Gao, Yuan,Li, Xuemei,Zhang, Xuejun C.,He, Zheng,Dong, Jing,Ke, Yuehua,Chen, Zeliang.

[8]A New Ni(II) Coordination Polymer Constructed by the Dicarboxylate and Imidazole-Containing Ligand With Three-Fold Interpenetrating pcu Topological Net: Synthesis, Crystal Structure, and Luminescent Property. Xu, Jiakun,Ju, Caixia,Zhang, Quan,Sun, Mi,Xu, Jiakun,Sun, Xiaochun,Ju, Caixia,Zhang, Quan.

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