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Chlorinated and brominated organic pollutants in shellfish from the Yellow Sea and East China Sea

文献类型: 外文期刊

作者: Yin, Ge 1 ; Asplund, Lillemor 1 ; Qiu, Yanling 2 ; Zhou, Yihui 2 ; Wang, Hua 2 ; Yao, Zongli 3 ; Jiang, Jianbin 4 ; Bergm 1 ;

作者机构: 1.Stockholm Univ, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden

2.Tongji Univ, Coll Environm Sci & Engn, Shanghai 200092, Peoples R China

3.Chinese Acad Fishery Sci, East China Sea Fisheries Res Inst, Shanghai 200090, Peoples R China

4.Tongzhou Fisheries Tech Instruct Stn Nantong, Nantong 226300, Peoples R China

关键词: Shellfish;Pesticides;HBCDD;DDT;MeO-PBDE;China

期刊名称:ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH ( 影响因子:4.223; 五年影响因子:4.306 )

ISSN:

年卷期:

页码:

收录情况: SCI

摘要: The global contamination with persistent organic pollutants (POPs), or compounds with similar characteristics, is well known. Still there are data gaps for POP concentrations from many areas in the world. The aim of the present study is to assess several legacies POPs and also hexabromocyclododecane (HBCDD) and methoxylated polybrominated diphenyl ethers (MeO-PBDEs) in shellfish from three locations in the Yellow Sea and East China Sea. The sources of the contaminants are discussed. Pooled samples were treated by liquid-liquid extraction and acid and column cleanup prior to analysis by gas chromatogram equipped with electron capture detector (GC-ECD) and gas chromatography-mass spectrometry (GC-MS). The by far most abundant environmental contaminant originates from dichlorodiphenyltrichloroethane (DDT), independent of species analyzed or sampling site. The results indicate ongoing or at least recent discharges of DDT. The second highest concentrations were reported for HBCDD (21-40 ng/g fat) in the shellfish, independent of sampling sites. The two natural products, 6-MeO-BDE-47 and 2'-MeO-BDE-68, were also present in the shellfish (1.3-22 and 1-14 ng/g fat, respectively). The polychlorinated biphenyl (PCB) congener CB-153 (0.8-6.5 ng/g fat), hexachlorobenzene (HCB) (1.1-3.6 ng/g fat), and beta-hexachlorocyclohexane (beta-HCH) (2.3-4.9 ng/g fat) were all higher than the concentrations of other HCH isomers, beta-endosulfan, PBDE congeners, and mirex. Apart from the DDTs and HBCDDs, it is evident that the pollution of shellfish was similar to, or lower than, the contamination of shellfish in other parts of the world.

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