MnO2/Polypyrrole/MnO2 multi-walled-nanotube-modified anode for high-performance microbial fuel cells
文献类型: 外文期刊
作者: Yuan, Haoran 1 ; Deng, Lifang 1 ; Chen, Yong 1 ; Yuan, Yong 2 ;
作者机构: 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Guangdong Inst Ecoenvironm & Soil Sci, Guangdong Key Lab Agr Environm Pollut Integrated, Guangzhou 510650, Guangdong, Peoples R China
3.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
关键词: multi-walled MnO2/polypyrrole/MnO2;nanotube;extracellular electrode transfer;electrochemical oxygen-reduction;electrochemical impedance spectroscopy
期刊名称:ELECTROCHIMICA ACTA ( 影响因子:6.901; 五年影响因子:6.016 )
ISSN:
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收录情况: SCI
摘要: Hierarchical multi-walled MnO2/polypyrrole/MnO2 nanotubes (NT-MPMs) were synthesized by a hydrothermal method and were decorated on a carbon cloth anode to promote microbial fuel cell (MFC) power production. Compared with bare carbon cloth (CK) anodes, the maximum power density of the MFC with an NT-MPM-decorated anode reaches 32.7 +/- 3 W/cm(3), which is approximately 1.3 times higher than that of the CK, and it exhibits excellent durability. The voltage outputs of the NT-MPM anode MFC decreased by 9.2% after being subjected to more than 90 full discharging-charging cycles. In additionbanode, which facilitated biofilm growth and promoted extracellular electron transfer between the bacteria and the electrode. Electrochemical impedance spectroscopy (EIS) measurements reveal that NT-MPM anodes lead to a low charge transfer resistance and provide unique active centers that host the bacteria for more efficient electrocatalysis. This study introduces a promising method for the fabrication of high-performance anodes from simple, inexpensive materials. (C) 2016 Elsevier Ltd. All rights reserved.
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