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A practical chromogenic and fluorogenic dual-mode sensing platform for rapid quantification of sulfite in food

文献类型： 外文期刊

作者： Yue, Chenyang 1 ; Zeng, Lintao 2 ; Zhang, Di 3 ; Li, Kai 2 ; Jiang, Lirong 4 ; Xie, Peng 1 ;

作者机构： 1.Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China

2.Guangxi Univ, Sch Light Ind & Food Engn, Nanning 530004, Peoples R China

3.Henan Acad Agr Sci, Inst Qual & Safety Agroprod, Zhengzhou 450002, Peoples R China

4.Guangxi Minzu Univ, Sch Chem & Chem Engn, Nanning 530006, Peoples R China

关键词： Fluorescent probe; Sulfite; Sensing platform; Smartphone; Food

期刊名称：FOOD CHEMISTRY （ 影响因子：8.8； 五年影响因子：8.6 ）

ISSN： 0308-8146

年卷期： 2024 年 440 卷

页码：

收录情况： SCI

摘要： Sulfur dioxide (SO2) and its derivatives (HSO3- and SO32-) are widely used in food-processing. Whereas excessive consumption of sulfur dioxide and its derivatives (>0.70 mgkg(-1)day(-1)) severely endangers human health. In this work, we rationally constructed a practical dual-mode probe (dicyanomethylene)-1-methyl-1,4-dihydroquinolin-2-yl)vinyl)-1-methylquinolinium (QMN), which underwent a specific 1, 4-Michael addition with sulfite to afford a noticeable color change from pale yellow to red along with a high-contrast fluorescence turn-on response at 598 nm. QMN has the advantages of rapid response, high signal-to-noise ratio, excellent selectivity, good water-solubility, large Stokes shift and low detection limit (LOD = 31.9 nM). QMN has been successfully used to on-site visually determine sulfite in a diversity of foods with satisfactory recoveries (91.33-111.33 %) and high accuracy (93.74-98.71 %). Furthermore, a portable smartphone-based fluorescence sensing platform was fabricated for on-site determination of sulfite in food with good performance.

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