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Preparation of Nitrogen-Doped Biomass-Based Carbon Quantum Dots and their Application to Fe3+ Detection and Bioimaging

文献类型: 外文期刊

作者: Lv, Rui 1 ; Wu, Liyu 1 ; Tian, Fuli 2 ; Bai, Hongmei 3 ; Huang, Dongke 1 ; Lei, Yanqiu 1 ; Liu, Fenrong 1 ;

作者机构: 1.Inner Mongolia Univ, Sch Chem & Chem Engn, Hohhot 010000, Peoples R China

2.Hainan Vocat Univ Sci & Technol, Key Lab Med & Edible Plants Resources Hainan Prov, Haikou 571126, Peoples R China

3.Inner Mongolia Acad Agr & Anim Husb Sci, Hohhot 010031, Peoples R China

关键词: Carbon Quantum Dots; Nitrogen-Doped; Sheep Manure; Ion Detection; High-Efficiency

期刊名称:JOURNAL OF FLUORESCENCE ( 影响因子:3.1; 五年影响因子:2.9 )

ISSN: 1053-0509

年卷期: 2025 年

页码:

收录情况: SCI

摘要: Carbon quantum dots are a new type of fluorescent material with promising application prospects in bioimaging, photocatalysis, and metal ions detection. Biomass is a plentiful and renewable natural resource containing a large amount of carbon, hydrogen and oxygen, and is an ideal precursor for the preparation of carbon quantum dots. Although biomass-based carbon dots possess numerous advantages, there are still several challenges. Specifically, the luminescence mechanism remains unidentified. Additionally, how to control the surface functionalization of biomass-based carbon dots is also a challenge. In this work, nitrogen-doped carbon quantum dots were synthesized sheep manure with glycine under optimized hydrothermal conditions to enhance nitrogen-containing functional groups. The results showed that the nitrogen-doped carbon quantum dots were synthesized when sheep manure mixed with glycine in a mass ratio of 4:1 and reacted at 240 degrees C for 12 h exhibited a quantum yield of 10.63%, a fluorescence lifetime of 7.82 ns, and exceptional stability-retaining fluorescence intensity above 630,855 a.u. after 30 days of storage. Furthermore, the nitrogen-doped carbon quantum dots exhibit high selectivity and sensitivity to Fe3+ (detection limit:4.7 mu M, linear range: 0-200 mu M) along with excellent bioimaging performance in L929 cells, demonstrating their dual-functional applications in both environmental sensing and bioimaging.

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