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Fabricated coordinate and ionic bonds in chemically cross-linked ethylene acrylic elastomer for high-performing elastomers

文献类型： 外文期刊

作者： Gao, Tianming 1 ; Yu, Biao 1 ; Hui, Yonghai 1 ; Chen, Jing 1 ; Chung, Kyungho 2 ; Wang, Sheng 1 ; Luo, Yongyue 3 ;

作者机构： 1.Lingnan Normal Univ, Key Lab Clean Energy Mat Chem Guangdong Higher Edu, Sch Chem & Chem Engn, Zhanjiang, Peoples R China

2.Univ Suwon, Dept Polymer Engn, Hwaseong, Gyeonggi-Do, South Korea

3.Chinese Acad Trop Agr Sci, Agr Prod Proc Res Inst, Zhanjiang, Peoples R China

4.Lingnan Normal Univ, Key Lab Clean Energy Mat Chem Guangdong Higher Edu, Sch Chem & Chem Engn, Zhanjiang 524048, Peoples R China

5.Chinese Acad Trop Agr Sci, Agr Prod Proc Res Inst, Zhanjiang 524001, Peoples R China

关键词： coordinate bond; ethylene acrylic elastomer; high-performance; ionic bond; magnesium oxide

期刊名称：POLYMER ENGINEERING AND SCIENCE （ 影响因子：2.573； 五年影响因子：2.352 ）

ISSN： 0032-3888

年卷期：

页码：

收录情况： SCI

摘要： Covalent bond cross-link networks endow rubber with unique resiliency enabling it to be widely used as a series of irreplaceable materials in modern life. However, the balance between rigidity and toughness, which is highly desired with the growing demand for high-performance rubber, remains a significant challenge for covalent bond networks. In this study, magnesium oxide (MgO) was filled in an ethylene acrylic elastomer (AEM) to construct both ionic cluster and coordinate bonds within the framework of a covalent cross-link network, which significantly improved the properties of AEM. The MgO-filled AEM was measured through Fourier transform infrared spectroscopy and thermogravimetric analysis, using a universal testing machine, dynamic mechanical thermal analyzer, and rubber process analyzer. As the multi-bond network was successfully constructed, the tensile strength was enhanced by almost 10 times, and unexpected dynamic properties were exhibited with a higher elastic modulus (rigidity) attributed to ionic clusters and a higher loss factor (toughness) attributed to the coordinate bonds. With the efficient enhancement of the mechanical properties, the improved toughness can dissipate energy to preserve the integrity of rubber under the application of an external mechanical force.

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