文献类型： 外文期刊

作者： Wang, Jian ³ ; Shi, Zefeng ³ ; Yuan, Guohui ⁴ ; Zhang, Nianlei ³ ; Xiao, Yanan ³ ; Jin, Zijin ³ ; Li, Mengdie ³ ; Wu, Wenneng ⁵ ; Yuan, Yongda ² ; Ren, Tianrui ³ ; Zhang, Bo ¹ ;

作者机构： 1.Shanghai Normal Univ, Shanghai Engn Res Ctr Green Energy Chem Engn, Coll Chem & Mat Sci, Key Lab Resource Chem,Minist Educ, 100 Guilin Rd, Shanghai 200234, Peoples R China

2.Shanghai Acad Agr Sci, Ecoenvironm Protect Res Inst, Shanghai 201403, Peoples R China

3.Shanghai Normal Univ, Coll Chem & Mat Sci, Shanghai Engn Res Ctr Green Energy Chem Engn, Key Lab Resource Chem,Minist Educ, Shanghai, Peoples R China

4.Shanghai Acad Agr Sci, Ecoenvironm Protect Res Inst, Shanghai, Peoples R China

5.Guiyang Univ, Food & Pharmaceut Engn Inst, Guiyang, Peoples R China

关键词： poly(urethane-urea) microcapsules; polyols and polyamine crosslinkers; wall thickness; controlled release

期刊名称：PEST MANAGEMENT SCIENCE （ 影响因子：4.1； 五年影响因子：4.4 ）

ISSN： 1526-498X

年卷期： 2024 年

页码：

收录情况： SCI

摘要： BACKGROUNDPolymeric microcapsules (MCs) have become an important issue and have attracted increasing attention because of their tunable physical and chemical properties. Diverse shell structures can confer multiple properties on MCs.RESULTSDifferent polyols (1,4-butanediol and glycerin) and polyamines (triethylenetetramine and isophorondiamine) were selected as crosslinkers to obtain emamectin benzoate (EB)-loaded poly(urethane-urea) MCs (PU-MCs) by interfacial polymerization. The four obtained PU-MCs showed sphericity with different degrees of smoothness on their surfaces, and displayed a uniform size distribution ranging from 500 to 700 nm. Moreover, transmission electron microscopy showed that the shell thickness was roughly uniform, and was greatly influenced by the type and structure of the crosslinker. GI-MCs, prepared using glycerin and isophorondiamine, had the largest shell thickness. GT-MCs, obtained using glycerin and triethylenetetramine, had the highest encapsulation efficiency and drug-loading content, and BT-MCs, obtained using mixtures of 1,4-butanediol and triethylenetetramine, had the fastest release behavior. Thermogravimetric analysis revealed that the greater the degree of shell crosslinking, the higher decomposition temperature and the greater the thermal stability. A BT-MC suspension had the lowest viscosity and contact angle with the best wettability. Bioassay experiments showed that BT-MCs exhibited good insecticidal activity against Plutella xylostella larvae with a half-maximal lethal concentration of 4.19 mg/L. Furthermore, a BT-MC suspension showed good thermal and light stability, with potential applications in minimizing the toxicity of EB through sustained release.CONCLUSIONVarious properties of EB-loaded PU-MCs were modulated through simple selection of different polyols and polyamines during fabrication, which might have an important role in constructing the pesticide delivery system and improving pesticide utilization. (c) 2024 Society of Chemical Industry. A new series of poly(urethane-urea) microcapsules (MCs) was constructed to investigate the relationships between MC structure and properties, providing a simple method of pesticide MC construction and effective controlled release of pesticides.dagger image