您好，欢迎访问中国热带农业科学院 机构知识库！
中国热带农业科学院机构知识库

全部

  • 全部
  • 标题
  • 学者
  • 机构
  • 关键词

Determination of azole fungicide residues in fruits and vegetables by magnetic solid phase extraction based on magnetic MOF sorbent in combination with high performance liquid chromatography

文献类型： 外文期刊

作者： Zhou, Dong-Dong 1 ; Cao, Yi-Wen 1 ; Chen, Min 1 ; Zhuang, Lv-Yun 1 ; Lv, Dai-Zhu 4 ; Wang, Ming-Yue 4 ; Yang, Zhong-Hua 1 ; Zeng, Yun-Liu 2 ;

作者机构： 1.Huazhong Agr Univ, Coll Plant Sci & Technol, Dept Plant Protect, Wuhan 430070, Peoples R China

2.Huazhong Agr Univ, Coll Hort & Forestry Sci, Wuhan 430070, Peoples R China

3.Huazhong Agr Univ, Coll Hort & Forestry Sci, Natl R&D Ctr Citrus Preservat, Natl Key Lab Germplasm Innovat & Utilizat Hort Cro, Wuhan, Peoples R China

4.Chinese Acad Trop Agr Sci, Anal & Testing Ctr, Haikou 571101, Peoples R China

关键词： Magnetic solid phase extraction (MSPE); DUT-5; High performance liquid chromatography; (HPLC); Azole fungicides; Fruits and vegetables

期刊名称：MICROCHEMICAL JOURNAL （ 影响因子：4.8； 五年影响因子：4.5 ）

ISSN： 0026-265X

年卷期： 2023 年 187 卷

页码：

收录情况： SCI

摘要： A sample pre-treatment technology, based on magnetic MOF composite Fe3O4@DUT-5 as the adsorbent, com-bined with high performance liquid chromatography (HPLC) has been developed and used for the trace analysis of azole fungicide residues in fruits and vegetables. Characterization analysis shows that Fe3O4@DUT-5 has good stability and excellent saturation magnetism. Under the optimal conditions, the satisfactory enrichment factors (69.6-96.4), and good linearity (10-1000 mu g L-1) could be achieved, as well as the low limits of detection (0.054 to 0.313 mu g L-1) were proved to be below the maximum residue limits (MRLs) of azole fungicides in agricultural products (10.0 mu g kg-1). Additionally, the proposed method has been successfully applied to the determination of target analytes in six fruits and vegetables. The achieved recovery (62.3-100.8%) and reproducibility (lower than 6.4%) meet the requirements of pesticide residue analysis. Moreover, the high adsorption capacity and stability remain unchanged after 5 cycles. And it has a strong saturation magnetization value, which provides a strong guarantee for recycling. As a novel adsorbent, Fe3O4@DUT-5 showed great potential in the extraction of pesticide residues in fruits and vegetables.

  • 相关文献
作者其他论文 更多>>
置顶
购物车
反馈

© 京ICP备09089781号-29 主办单位：中国热带农业科学院

学术资源： 中国农业科学院 农业专业知识服务系统 农科联盟资源共建共享平台 中国农业科技文献与信息服务平台 中国农业期刊集成服务平台