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Facile synthesis of spiro thiazolidinone via cyclic ketones, amines and thioglycolic acid by MCM-41-Schiff base-CuSO4 center dot 5H(2)O

文献类型： 外文期刊

作者： Hui, Yonghai 1 ; Zhang, Yongfei 1 ; Luo, Yongyue 2 ; Li, Jianpeng 1 ; Wang, Yun 1 ; Gao, Tianming 1 ; Xia, Jialiang 1 ; W 1 ;

作者机构： 1.Lingnan Normal Univ, Coll Chem & Chem Engn, Key Lab Clean Energy Mat Chem, Guangdong Higher Educ Inst, Zhanjiang 524048, Peoples R China

2.Chinese Acad Trop Agr Sci, Agr Prod Proc Res Inst, Zhanjiang 524001, Peoples R China

关键词： Heterogeneous; MCM-41; Schiff base; Thiazole; Condensation

期刊名称：RESEARCH ON CHEMICAL INTERMEDIATES （ 影响因子：2.914； 五年影响因子：2.32 ）

ISSN： 0922-6168

年卷期：

页码：

收录情况： SCI

摘要： Mesoporous MCM-41-supported Schiff base and CuSO(4)Greek ano teleia5H(2)O (MCM-41@Schiff base-CuSO(4)Greek ano teleia5H(2)O) catalyzed one-pot three-component condensation of cyclic ketones, amines and thioglycolic acid in toluene. And a series of corresponding spiro thiazolidinone derivatives were obtained in high yields (up to 97%). The synthesized catalyst was characterized via FT-IR, XRD, SEM, TEM and EDS and can be easily recovered by centrifugation and reused at 10 times without any change in catalytic activity. Moreover, the scale-up experiment also demonstrated the practicability of the catalytic system on the condensation. The possible mechanisms pave the way to investigation on the reactions of other cyclic ketones with thioglycolic acid.

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