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Impact of Molecular Ligands in the Synthesis and Transformation between Metal Halide Perovskite Quantum Dots and Magic Sized Clusters

文献类型: 外文期刊

作者: Liu, Li 1 ; Pan, Keliang 4 ; Xu, Ke 3 ; Zhang, Jin Z. 2 ;

作者机构: 1.Hubei Acad Agr Sci, Res Inst Agr Qual Stand & Testing Technol, Wuhan 430064, Peoples R China

2.Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA

3.Chinese Acad Sci, Shenzhen Inst Adv Technol, Multiscale Crystal Mat Res Ctr, Shenzhen 518055, Peoples R China

4.Hubei Inst Geosci, Wuhan 430034, Peoples R China

5.Hubei Key Lab Resource & Ecol Environm Geol, Wuhan 430034, Peoples R China

关键词: perovskite; quantum dots; magic; sized clusters; capping ligands; surface passivation; transformation

期刊名称:ACS PHYSICAL CHEMISTRY AU

ISSN:

年卷期: 2022 年 2 卷 3 期

页码:

收录情况: SCI

摘要: Metal halide perovskite quantum dots (PQDs) and perovskite magic sized clusters (PMSCs) exhibit interesting size- and composition-dependent optoelectronic properties that are promising for emerging applications including photovoltaic solar cells and light-emitting diodes (LEDs). Much work has focused on developing new synthesis strategies to improve their structural stability and property tunability. In this paper, we review recent progress in the synthesis and characterization of PQDs and PMSCs, with a focus on the impact of different molecular ligands on their surface passivation and interconversion. Moreover, the effect of capping ligands on ion exchange during synthesis and doping is discussed. Finally, we present some perspectives on challenges and opportunities in fundamental studies and potential applications of both PQDs and PMSCs.

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