Fe3O4@COF(TAPT-DHTA) Nanocomposites as Magnetic Solid-Phase Extraction Adsorbents for Simultaneous Determination of 9 Mycotoxins in Fruits by UHPLC-MS/MS
文献类型： 外文期刊
作者： Wang, Jie 1 ; Huang, Qingwen 2 ; Guo, Wenbo 2 ; Guo, Dakai 2 ; Han, Zheng 2 ; Nie, Dongxia 1 ;
作者机构： 1.Univ Shanghai Sci & Technol, Sch Hlth Sci & Engn, Shanghai 200093, Peoples R China
2.Shanghai Acad Agr Sci, Inst Agrofood Stand & Testing Technol, Shanghai 201403, Peoples R China
关键词： covalent organic framework; magnetic solid-phase extraction; mycotoxins; UHPLC-MS; MS; fruits
期刊名称：TOXINS （ 影响因子：4.2； 五年影响因子：4.7 ）
ISSN：
年卷期： 2023 年 15 卷 2 期
页码：
收录情况： SCI
摘要： In this study, a simple and efficient magnetic solid-phase extraction (MSPE) strategy was developed to simultaneously purify and enrich nine mycotoxins in fruits, with the magnetic covalent organic framework nanomaterial Fe3O4@COF(TAPT-DHTA) as an adsorbent. The Fe3O4@COF(TAPT-DHTA) was prepared by a simple template precipitation polymerization method, using Fe3O4 as magnetic core, and 1,3,5-tris-(4-aminophenyl) triazine (TAPT) and 2,5-dihydroxy terephthalaldehyde (DHTA) as two building units. Fe3O4@COF(TAPT-DHTA) could effectively capture the targeted mycotoxins by virtue of its abundant hydroxyl groups and aromatic rings. Several key parameters affecting the performance of the MSPE method were studied, including the adsorption solution, adsorption time, elution solvent, volume and time, and the amount of Fe3O4@COF(TAPT-DHTA) nanomaterial. Under optimized MSPE conditions, followed by analysis with UHPLC-MS/MS, a wide linear range (0.05-200 mu g kg(-1)), low limits of detection (0.01-0.5 mu g kg(-1)) and satisfactory recovery (74.25-111.75%) were achieved for the nine targeted mycotoxins. The established method was further successfully validated in different kinds of fruit samples.
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