Hydrothermal temperature-dependent compositions and copper complexing behaviors of hydrochar-derived dissolved organic matter: Insights from FT-ICR MS and multi-spectroscopic analysis
文献类型： 外文期刊
作者： Chen, Bingfa 1 ; Gu, Xincai 2 ; Feng, Muhua 4 ; Feng, Yanfang 2 ; Wang, Bingyu 5 ; You, Bensheng 1 ; Zheng, Jingcheng 2 ; Liu, Hong 3 ; Han, Shiqun 2 ;
作者机构： 1.State Environm Protect Key Lab Aquat Ecosyst Hlth, Nanjing 210093, Peoples R China
2.Jiangsu Acad Agr Sci, Key Lab Agroenvironm Downstream Yangtze Plain, Minist Agr & Rural Affairs, Inst Agr Resources & Environm, Nanjing 210014, Peoples R China
3.Suzhou Univ Sci & Technol, Sch Environm Sci & Engn, Suzhou 215009, Peoples R China
4.Chinese Acad Sci, State Key Lab Lake Sci & Environm, Nanjing Inst Geog & Limnol, Nanjing 210008, Peoples R China
5.Nanjing Univ Sci & Technol, Sch Environm & Biol Engn, Nanjing 210094, Peoples R China
6.Yancheng Teachers Univ, Jiangsu Synthet Innovat Ctr Coastal Bioagr, Sch Wetlands, Yancheng 224002, Peoples R China
关键词： Hydrochar; Dissolved organic matter; Molecular characterizations; Cu(II) binding; Two-dimensional correlation analysis (2D-COS)
期刊名称：JOURNAL OF ENVIRONMENTAL SCIENCES （ 影响因子：6.3； 五年影响因子：6.1 ）
ISSN： 1001-0742
年卷期： 2025 年 152 卷
页码：
收录情况： SCI
摘要： The copper complexing of dissolved organic matter released from hydrochar (HDOM) affects the former's environmental behavior. In this study, how hydrothermal temperatures (180, 220 and 260 degrees C) influence the molecular-level constitutions and Cu(II) binding features of HDOM were elucidated via fourier transform ion cyclotron resonance mass spectrometry and multi-spectroscopic analysis. The findings demonstrated that the almost HDOM molecules had the traits of lower polarity and higher hydrophobicity. As the hydrothermal temperature increased, the molecules with particularly high relative strength gradually disappeared, average molecular weight, percentages of CHON and aliphatic compounds of HDOM reduced while the percentages of CHO and aromatic compounds increased. In general, the fluorescence quenching of Cu(II) weakened as hydrothermal temperature rose and the Cu(II) binding stability constants of fluorophores in HDOM were 4.50-5.31. In addition, the Cu(II) binding order of fluorophores in HDOM showed temperature heterogeneities, and polysaccharides or aromatic rings of non-fluorescent substances had the fastest responses to Cu(II) binding. Generally, fluorescent components tend to bind Cu(II) at relatively trace concentrations (0-40 mu mol/L), whereas non-fluorescent substances tend to the bind Cu(II) at relatively higher concentrations (50-100 mu mol/L). This study contributed to the prediction of the potential environmental behaviors and risks of Cu(II) at the molecular level after hydrochar application. (c) 2024 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.
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