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In situ synthesis of VS4/Ti3C2Tx MXene composites as modified separators for lithium-sulfur battery

文献类型： 外文期刊

作者： Chen, Dong 1 ; Zhu, Tianjiao 2 ; Shen, Shen 1 ; Cao, Yongan 2 ; Mao, Yangyang 2 ; Wang, Wenju 2 ; Bao, Encai 3 ; Jiang, Hongfu 1 ;

作者机构： 1.Jiangsu Xinhua Semicond Technol Co Ltd, Xuzhou, Peoples R China

2.Nanjing Univ Sci & Technol, Sch Energy & Power Engn, Nanjing 210094, Peoples R China

3.Jiangsu Acad Agr Sci, Inst Agr Facil & Equipment, Nanjing 210014, Peoples R China

关键词： Lithium-sulfur batteries; Modified separators; VS4; Polysulfides shuttle effect; Catalysis transformation

期刊名称：JOURNAL OF COLLOID AND INTERFACE SCIENCE （ 影响因子：9.9； 五年影响因子：8.4 ）

ISSN： 0021-9797

年卷期： 2023 年 650 卷

页码：

收录情况： SCI

摘要： Lithium-sulfur (Li-S) batteries are regarded as highly prospective energy storage devices. However, problems such as low sulfur utilization, poor cycle performance, and insufficient rate capability hinder the commercial development of Li-S batteries. Three-dimensional (3D) structure materials have been applied to modify the separator of Li-S batteries to suppress the diffusion of lithium polysulfides (LiPSs) and inhibit the transmembrane diffusion of Li+. A vanadium sulfide/titanium carbide (VS4/Ti3C2Tx) MXene composite with a 3D conductive network structure has been synthesized in situ by a simple hydrothermal reaction. VS4 is uniformly loaded on the Ti3C2Tx nanosheets through vanadium-carbon(V-C) bonds, which effectively inhibits the self-stacking of Ti3C2Tx. The synergistic action of VS4 and Ti3C2Tx substantially reduces the shuttle of LiPSs, improves interfacial charge transfer, and boosts the kinetics of LiPSs conversion, consequently increasing the rate performance and cycle stability of the battery. The assembled battery has a specific discharge capacity of 657 mAh g-1 after 500 cycles at 1C, with a high capacity retention rate of 71%. The construction of VS4/Ti3C2Tx composite with a 3D conductive network structure provides a feasible strategy for the application of polar semiconductor materials in Li-S batteries. It also provides an effective solution for the design of high-performance Li-S batteries.

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