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A novel Fe-PTFE magnetic composite prepared by ball milling for the efficient degradation of imidacloprid: Insights into interaction mechanisms based on ultrasonic piezoelectric catalysis

文献类型： 外文期刊

作者： He, Liuyang 1 ; Wu, Lijuan 1 ; Shen, Shitai 1 ; Li, Yulong 1 ; Chen, Siyu 1 ; Xue, Jianming 2 ; Yang, Shengmao 4 ; Zhang, Zulin 1 ; Wu, Li 1 ; Yang, Lie 1 ;

作者机构： 1.Wuhan Univ Technol, Sch Resources & Environm Engn, Hubei Key Lab Mineral Resources Proc & Environm, Wuhan 430070, Peoples R China

2.New Zealand Forest Res Inst Scion, Forest Syst, POB 29237, Christchurch 8440, New Zealand

3.Nanjing Forestry Univ, Coll Biol & Environm, Nanjing 210037, Peoples R China

4.Zhejiang Acad Agr Sci, Inst Environm Resource Soil & Fertilizer, 198 Shiqiao Rd, Hangzhou 310021, Peoples R China

5.James Hutton Inst, Aberdeen ABI5 8QH, Scotland

关键词： Piezocatalytic; PTFE particles; Ball-milling; Fe0 powder; Ultrasonic

期刊名称：SCIENCE OF THE TOTAL ENVIRONMENT （ 影响因子：9.8； 五年影响因子：9.6 ）

ISSN： 0048-9697

年卷期： 2023 年 864 卷

页码：

收录情况： SCI

摘要： In this study, a novel magnetic poly (tetrafluoroethylene, PTFE) (Fe@PTFE) piezoelectric catalytic material was suc-cessfully prepared by a simple ball milling treatment. The prepared piezoelectric catalytic material Fe@PTFE exhibited excellent catalytic performance under the activation of ultrasonic (US) and realized the efficient degradation of imidacloprid (IMI) at low concentrations in an aqueous environment. It was demonstrated by various characterization methods that Fe0 was successfully loaded onto PTFE particles (1-15 mu m) by ball milling. The US/Fe@PTFE system ex-hibited superior IMI degradation efficiency (99 %) and degradation rate (7.81x 10-2 min-1) under ultrasonic polar-ization with high efficiences of IMI degradation after five cycles. In addition, the system maintained excellent removal efficiencies in the real water matrixes. The mechanism study demonstrated that Fe@PTFE generated a variety of reac-tive oxygen species (center dot OH, 1O2 and O2 center dot-) and H2O2 under the irradiation of US, and the production of H2O2 provided the conditions for the continuation of the Fenton-like reaction. Furthermore, the presence of O2 center dot-in the system enhanced the recycling efficiency of Fe(III) and Fe(II), which further enhanced the degradation efficiency of the Fenton-like pro-cess. This study provides a novel perspective on a PTFE-based ultrasonic piezoelectric catalytic system for the efficient removal of organic pollutants in the environmental field.

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