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Interactions between lead(II) ions and dissolved organic matter derived from organic fertilizers incubated in the field

文献类型: 外文期刊

作者: Chen, Long 1 ; Li, Boling 1 ; Wu, Zhipeng 1 ; Zhao, Qingjie 1 ; Wang, Qiuyue 1 ; Wang, Hailong 2 ; Singh, Bhupinder Pal 3 ; Wu, Weidong 1 ; Fu, Chuanliang 4 ;

作者机构: 1.Hainan Univ, Coll Trop Crops, Haikou 570228, Hainan, Peoples R China

2.Foshan Univ, Sch Environm & Chem Engn, Foshan 528000, Peoples R China

3.Elizabeth Macarthur Agr Inst, Dept Primary Ind, Menangle, NSW 2568, Australia

4.Hainan Acad Agr Sci, Inst Agr Environm & Soil, Haikou 571100, Hainan, Peoples R China

5.Key Lab Arable Land Conservat Hainan Prov, Haikou 571100, Hainan, Peoples R China

关键词: DOM; Commercial organic fertilizer; Parallel factor analysis; Two-dimensional correlation; spectroscopy; Lead (Pb)

期刊名称:JOURNAL OF ENVIRONMENTAL SCIENCES ( 影响因子:6.796; 五年影响因子:6.127 )

ISSN: 1001-0742

年卷期: 2022 年 121 卷

页码:

收录情况: SCI

摘要: This work was to study composition characteristics and the subsequent effect on the lead (Pb) binding properties of dissolved organic matter (DOM) derived from seaweed-based (SWOF) and chicken manure organic fertilizers (CMOF) during a one-year field incubation experiment using the excitation-emission matrix-parallel factor (EEM-PARAFAC) and twodimensional correlation spectroscopy (2DCOS) analysis. Results showed that high aromatic and hydrophobic fluorescent substances were enriched in CMOF-derived DOM and SWOFderived DOM and enhanced over time. And phenolic groups in the fulvic-like substances for SWOF-derived DOM and carboxyl groups in the humic-like substances for CMOF-derived DOM had the fastest responses over time, respectively. Moreover, both non-fluorescent polysaccharides and fluorescent humic-like substances or fulvic-like substances with aromatic (C = C) groups first participated in the binding process of Pb to SWOF-derived DOM on day 0 and 180 during the lead binding process. In contrast, humic-like substances associated with aromatic (C = C) and phenolic groups gave a faster response to Pb binding on day 360. Regarding CMOF-derived DOM, the fulvic-like substances associated with aromatic (C = C) and carboxylic groups displayed a faster response to Pb ions on day 0. Nonetheless, polysaccharides and humic-like associated with phenolic groups had a faster response on days 180 and 360. It is noteworthy that the polysaccharides, which participated in Pb binding to CMOF-derived DOM, posed a higher risk of Pb in the environment after 360 days. Therefore, these findings gave new insights into the long-term applications of commercial organic fertilizers for the amendment of soil. ?? 2022 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.

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