A sensor based on Fe/B/N codoped hierarchical porous carbon spheres that amplify the aggregation-induced electrochemiluminescence of calcein for florfenicol trace detection
文献类型： 外文期刊
作者： Deng, Yan 1 ; Pang, Chaohai 2 ; Li, Shuhuai 1 ; Ma, Xionghui 2 ; Wu, Yuwei 2 ; Zhang, Lianming 1 ; Li, Jianping 1 ;
作者机构： 1.Guilin Univ Technol, Coll Chem & Bioengn, Guilin 541004, Peoples R China
2.Chinese Acad Trop Agr Sci, Anal & Test Ctr, Hainan Prov Key Lab Quality & Safety Trop Fruits &, Key Lab Quality & Safety Control Subtrop Fruits &, Haikou 571101, Peoples R China
关键词： Aggregation -induced; electrochemiluminescence; Porous carbon spheres; Calcein; Florfenicol; Sensor
期刊名称：MICROCHEMICAL JOURNAL （ 影响因子：4.8； 五年影响因子：4.5 ）
ISSN： 0026-265X
年卷期： 2024 年 199 卷
页码：
收录情况： SCI
摘要： Electrochemiluminescence (ECL) signal amplification is an important method for improving sensor sensitivity. In this study, an ECL sensor was developed for florfenicol detection based on the aggregation-induced electrochemiluminescence of calcein and Fe/B/N codoped hierarchical porous carbon spheres (B-N-Fe-HPCs). First, BN-Fe-HPCs were prepared by a simple high-temperature synthesis method, attached to the gold electrode surface, and used as a signal amplification element. Then, a molecularly imprinted polymer (MIP) was prepared using florfenicol as a template molecule and phthalylenediamine as a functional monomer and doped with calcein on the B-N-Fe-HPC-modified electrode. After the elution of florfenicol, the sensor retains an imprinted site that specifically recognizes florfenicol can readsorb florfenicol in the sample. Because calcein aggregates in the MIP to generate an ECL signal, B-N-Fe-HPCs effectively amplifies this ECL signal. Thus, because the ECL signal of the sensor can be quenched, a new method for detecting florfenicol was established. The sensor used for florfenicol showed very high sensitivity and good selective performance, with a linear range of 1-8000 x 10-12 mol/L and a detection limit of 4.65 x 10-13 mol/L. The sensor was applied to detect actual samples, such as chicken, and the results were satisfactory, with the recovery rate of the spike from 91.2 % to 105.3 %.
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