文献类型： 外文期刊
作者： Wang Li 1 ; Chang Gong-Min 3 ; Xue Xiao-Yan 1 ; Huang Shu-Ping 1 ; Chen Xia 1 ;
作者机构： 1.Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China
2.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
3.Shanxi Acad Agr Sci, Agr Utilizat Res Inst, Taiyuan 030037, Peoples R China
关键词： synthesis;structure;lithium complex;mechanism
期刊名称：CHINESE JOURNAL OF INORGANIC CHEMISTRY （ 影响因子：0.834； 五年影响因子：0.604 ）
ISSN： 1001-4861
年卷期： 2011 年 27 卷 5 期
页码：
收录情况： SCI
摘要： A novel hexanuclear cage lithium complex 3 was synthesized by addition reaction of [PhN(SiMe(2)(OMe))Li](2) with piperidyl nitrite and its crystal structure was determined. Compound 3 was characterized by (1)H NMR spectra and X-ray diffraction patterns. The crystal of compound 3 shows a cage structure and belongs to monoclinic space group: P2(1)/n, with a=1.248 83(19) nm, b=1.402 7(2) nm, c=1.853 4(3) nm; beta=95.894(2)degrees; V=3229.5(8) nm(3), Z=2, R(1)=0.047 7, GOF=0.946. CCDC: 816546.
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