Prediction and evolution of core-shell morphology and their effect on mechanical properties of PP blends
文献类型： 外文期刊
作者： Chen, Xunwei 1 ; Li, Zhi 1 ; Qiu, Biwei 1 ; Shi, Jiangao 2 ;
作者机构： 1.Univ Shanghai Sci & Technol, Sch Mat & Chem, Shanghai, Peoples R China
2.Chinese Acad Fishery Sci, East China Sea Fisheries Res Inst, Shanghai, Peoples R China
3.Univ Shanghai Sci & Technol, Sch Mat & Chem, 516 Jungong Rd, Shanghai 200093, Peoples R China
关键词： Elastomer; polypropylene; core-shell structure; compatibility; fracture toughness
期刊名称：JOURNAL OF REINFORCED PLASTICS AND COMPOSITES （ 影响因子：3.1； 五年影响因子：3.6 ）
ISSN： 0731-6844
年卷期： 2023 年
页码：
收录情况： SCI
摘要： The prediction of phase morphology is highly valuable in designing and regulating the properties of multiphase composites, particularly polymer blends. In this study, we prepared two types of ternary blends, PP/HDPE/EPR and PP/HDPE/EPDM composites and compared and analyzed the predicted and observed phase morphology of blends with different elastomers. Using Palierne and Bousmina equations, we calculated the interfacial tensions between two components in PP blends and then predicted the relationship between the spreading coefficient, interfacial tension, and phase morphology according to the spreading coefficient theory. Based on our findings, it was observed that the core-shell structure of EPR and EPDM rubber phase encapsulated HDPE core tends to form in PP ternary blends, which aligns with our experimental results. Additionally, SEM morphology observation results revealed a less number of dispersed phases in PP/HDPE/EPR composites with the same composition ratio. It was observed that the shell had a greater thickness due to the difficulty in dispersing EPR with higher viscosity. Mechanical tests indicated that composites with thin-shell and small-core dispersed phases had better toughness. These composites also displayed less yield strength loss under the same impact conditions compared to those with single rubber phases.
- 相关文献
作者其他论文 更多>>
-
Selectivity of crab pots with escape vents and the optimal vent height for reducing the catch of sublegal swimming crab in the East China Sea pot fishery
作者：Zhang, Jian;Zhang, Honglin;Fei, Jiaojiao;Chu, Wenhua;Zhang, Jian;Chu, Wenhua;Zhang, Jian;Chu, Wenhua;Zhang, Jian;Chu, Wenhua;He, Pingguo;Shi, Jiangao
关键词：Size selectivity; Crab pots; Escape vent; Portunus trituberculatus; Optimal vent height; Exploitation pattern; SELECT model
-
Enhancing the marine antifouling property of high-density polyethylene through melt grafting of poly (hexamethylene guanidine)
作者：Wang, Jiaqi;Yu, Wenwen;Liu, Wenying;Wang, Guofeng;Shi, Jiangao;Wang, Hong
关键词：Marine antifouling; Nonpoisonous; Nonleaching; (LCB) long -chain branch
-
Metabolomics analysis of physicochemical properties associated with freshness degradation in frozen Antarctic krill (Euphausia superba)
作者：Ni, Ling;Jiang, Chaojun;Guo, Quanyou;Chi, Hai;Fan, Chengqi;Shi, Jiangao;Lin, Na;Liu, Zhidong;Chen, Shengjun
关键词：Frozen Antarctic krill; Physicochemical properties; Non-targeted metabolomics; Quality degradation
-
Synthesis of core-shell ZnO nanoparticles and their effect on mechanical and antibacterial properties for PLLA/ZnO nanocomposites
作者：Liu, Zhilin;Chen, Xunwei;Ling, Wei;Wang, Meng;Qiu, Biwei;Wang, Meng;Shi, Jiangao;Qiu, Biwei
关键词：antibacterial properties; core-shell structure; PLLA; toughness; ZnO
-
PPR/EPDM/POE-g-MA/OMMT nanocomposites with superior low-temperature toughness based on embedded OMMT within compound rubber dispersion phase
作者：Qiu, Biwei;Li, Zhi;Li, Zhi;Chen, Feng;Shangguan, Yonggang;Zheng, Qiang;Shi, Jiangao;Zhang, Mingyu;Zheng, Qiang;Shangguan, Yonggang;Zheng, Qiang
关键词：Low-temperature toughening; Synergistic effect; Compound rubber
-
The Assessment of Withdrawal Interval for Enrofloxacin in Yellow Catfish (Pelteobagrus fulvidraco) after Multiple Oral Administrations at Disparate Temperatures
作者：Xu, Ning;Sun, Weiyu;Zhang, Huan;Li, Zhi;Ai, Xiaohui;Sun, Weiyu;Zhang, Huan;Li, Zhi;Cheng, Bo;Ding, Yongzhen
关键词：withdrawal time; enrofloxacin; ciprofloxacin; yellow catfish; different temperatures
-
Effects of Temperature on Plasma Protein Binding Ratios (PPBRs) of Enrofloxacin and Ciprofloxacin in Yellow Catfish (Pelteobagrus fulvidraco), Grass Carp (Ctenopharyngodon idella), and Largemouth Bass (Micropterus salmoides)
作者：Xu, Ning;Sun, Weiyu;Zhang, Huan;Li, Zhi;Luo, Xiangzhong;Ai, Xiaohui;Sun, Weiyu;Zhang, Huan;Li, Zhi;Ding, Yongzhen;Cheng, Bo
关键词：PPBRs; enrofloxacin; ciprofloxacin; finfish; temperatures; concentrations
