文献类型： 外文期刊

作者： Liu, Q. F. ¹ ; Li, F. Z. ¹ ; Guo, Y. Q. ¹ ; Dong, Y. L. ¹ ; Liu, J. Y. ¹ ; Shao, H. B. ² ; Fu, Z. M. ¹ ;

作者机构： 1.Inner Mongolia Univ, Coll Environm & Resources, 235 West Coll Rd, Inner Mongolia 010021, Hohhot, Peoples R China

2.Chinese Acad Sci, Key Lab Coastal Biol & Bioresources Utilizat, Yantai Inst Coastal Zone Res YIC, Yantai 264003, Peoples R China

3.Jiangsu Acad Agr Sci, Inst Biotechnol, Nanjing 210014, Jiangsu, Peoples R China

关键词： PVDF;alkaline treatment;blend;hydrophilicity

期刊名称：MEMBRANE WATER TREATMENT （ 影响因子：1.0； 五年影响因子：0.923 ）

ISSN： 2005-8624

年卷期： 2016 年 7 卷 5 期

页码：

收录情况： SCI

摘要： Poly(vinylidene fluoride) (PVDF) powder was treated with aqueous sodium hydroxide to obtain partially defluorinated fluoropolymers with expected properties such as improving hydrophilicity and fouling resistance. Raman spectrum and FT-IR results confirmed the existence of conjugated carbon double bonds after alkaline treatment. As the concentration increased, the degree of defluorination increased. The morphology and structure of membranes were examined. The permeation performance was investigated. The results showed that membrane's hydrophilicity increased with increase of the percentage of alkaline treated PVDF powder. Moreover, in terms of the water contact angle, it decreased from 92 degrees to a minimum of 68 degrees; while water up take increased from 128 to 138%. Fluxof pure water and the cleaning efficiency increased with the increase of alkaline treated PVDF powder. The fouling potential also decreased with the increase of the percentage of alkaline treated PVDF powder. The reason that makes blending PVDF show different characteristics because of partial defluorination, which led the formation of conjugated C = C bonds and the inclusion of oxygen functionalities. The polyene structure followed by hydroxide attack to yield hydroxyl and carbonyl groups. Therefore, the hydrophilicity of blending membrane was improved. The SEM and porosity measurements showed that no obvious variations of the pore dimensions and structures for blend membranes were observed. Mechanical tests suggest that the high content of the alkaline treated PVDF result in membranes with less tolerance of tensile stress and higher brittleness. TGA results exhibited that the blend of alkaline treated PVDF did not change membrane thermal stability.