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Bis(mu(2)-pyridine-2-carboxamide oximato)bis[(pyridine-2-carboxamide oxime)zinc] dinitrate

文献类型: 外文期刊

作者: Deng, Xiao-Hui 1 ; Ran, Jing-Wen 2 ;

作者机构: 1.Hubei Acad Agr Sci, Inst Cash Crops, Wuhan 430064, Peoples R China

2.Dalian Univ Technol, Key Lab Ind Ecol & Environm Engn MOE, Sch Environm Sci & Technol, Dalian 116024, Peoples R China

3.Dalian Univ Technol, State Key Lab Fine Chem, Sch Environm Sci & Technol, Dalian 116024, Peoples R China

期刊名称:ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE ( 影响因子:0.347; 五年影响因子:0.278 )

ISSN: 1600-5368

年卷期: 2011 年 67 卷

页码:

收录情况: SCI

摘要: In the title dinuclear compound, [Zn-2(C6H6N3O)(2)(C6H7N3O)(2)](NO3)(2), the Zn-II cation is N,N'-chelated by one pyridine-2-carboxamide oximate anion and one pyridine-2-carboxamide oxime molecule, and is further bridged by an oxime O atom from the adjacent pyridine-2-carboxamide oximate anion, forming a distorted trigonal bipyramidal coordination. Two pyridine-2-carboxamide oximate anions bridge two Zn-II cations to form the centrosymmetric dinuclear molecule. Extensive O-H center dot center dot center dot O, N-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds are present in the crystal structure.

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