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Poly(sodium 4-styrenesulfonate) modified carbon nanoparticles by a thermo-mechanical technique and its reinforcement in natural rubber latex

文献类型： 外文期刊

作者： He, Xuelian 1 ; Peng, Zheng 2 ; Yu, Na 1 ; Han, Jingjie 1 ; Wu, Chifei 1 ;

作者机构： 1.E China Univ Sci & Technol, Polymer Alloy Lab, Shanghai 200237, Peoples R China

2.Chinese Acad Trop Agr Sci, Agr Prod Proc Res Inst, Chinese Agr Minist Key Lab Nat Rubber Proc, Zhanjiang 524001, Peoples R China

关键词： Thermo-mechanical;Sodium 4-styrenesulfonate;Natural rubber latex;Polymer-matrix composite (PMCs);Mechanical properties

期刊名称：COMPOSITES SCIENCE AND TECHNOLOGY （ 影响因子：8.528； 五年影响因子：7.907 ）

ISSN： 0266-3538

年卷期： 2008 年 68 卷 14 期

页码：

收录情况： SCI

摘要： A novel strategy of radical polymerization of sodium 4-styrenesulfonate (NASS) on the surface of carbon black (CB) in solid state is developed to prepare water-soluble carbon nanoparticles (PNASS-CBs). Fourier transform infrared spectroscopy (FT-IR) and proton nuclear magnetic resonance (H-1 NMR) results show the presence of PNASS chains on the surface of CBs. The PNASS-CBs are homogenously distributed throughout water as nanoclusters with an average size of 90 nm when the PNASS-CB concentration is less than 10 wt% Furthermore, a high performance of natural rubber latex (NRL)/PNASS-CB composite is gained by latex compounding technique; the carbon nanoparticles are uniformly dispersed in the latex. When compared to the NRL/pristine CB composite (CB loading 30 phr) the tear strength, tensile strength and elongation at break of the obtained composite is increase by 185%, 130% and 120%, respectively. (C) 2008 Elsevier Ltd. All rights reserved.

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