Pyrrolidinium Ionic Liquids as Effective Solvents for Lignin Extraction and Enzymatic Hydrolysis of Lignocelluloses
文献类型: 外文期刊
作者: Hu, Xiao-Mei 1 ; Li, Shuang 1 ; Ma, Hui-Hui 1 ; Zhang, Bi-Xian 2 ; Gao, Yun-Fei 2 ;
作者机构: 1.Northeast Agr Univ, Coll Life Sci, Harbin 150030, Peoples R China
2.Heilongjiang Acad Agr Sci, Harbin 150086, Peoples R China
关键词: Ionic liquids;Lignocelluloses;Pretreatment;Pyrrolidinium
期刊名称:BIORESOURCES ( 影响因子:1.614; 五年影响因子:1.923 )
ISSN: 1930-2126
年卷期: 2016 年 11 卷 3 期
页码:
收录情况: SCI
摘要: Lignocellulosic biomass as a renewable and valuable resource has been a very active research area during recent years. Ionic liquids (ILs) are an attractive approach for the pretreatment of lignocelluloses. In this work, a series of pyrrolidinium-based ionic liquids were prepared simply and were investigated for the pretreatment of corn stalk at 90 degrees C for 30 min. The characteristics of regenerated lignin and cellulose-rich materials were determined by Fourier transform infrared spectroscopy (FTIR) analysis. Both ILs and ILs/H2O were studied. Notably, 10.17% lignin based on the original corn stalk was recovered with [Hmp] Cl-pretreatment; 21.34% and 15.83% reducing sugar based on the original corn stalk were observed during pretreatment with [Hmp]HSO4/H2O and [Hmp]Cl/H2O pretreatment, respectively; 80.54% of reducing sugar was obtained based on the cellulose-rich materials with [Hmp]Cl/H2O-pretreatment. Also, the glucose and cellobiose yields were 73.82% and 8.64%, respectively.
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