High-concentration single-atom Zn-doped porous tubular g-C3N4: a superior photocatalyst for tetracycline hydrochloride degradation and bacterial sterilization
文献类型： 外文期刊
作者： Li, Chunyan 1 ; Cai, Yuxing 1 ; Wu, Jianhao 1 ; Li, Lan 1 ; Xia, Sa-Sa 1 ; Wang, Xiaozhuo 1 ; Jia, Rongrong 1 ; Chen, Zhi 1 ; Jin, Cheng-Chao 1 ; Wang, Wen 2 ; Wang, Rongyan 4 ; Zhang, Nan 1 ;
作者机构： 1.China Jiliang Univ, Coll Mat & Chem, Hangzhou 310018, Peoples R China
2.China Jiliang Univ, Coll Life Sci, Hangzhou 310018, Peoples R China
3.Zhejiang Acad Agr Sci, Inst Agroprod Safety & Nutr, State Key Lab Managing Biot & Chem Threats Qual &, MOA Lab Qual & Safety Risk Assessment Agroprod Han, Hangzhou 310021, Peoples R China
4.Chinese Acad Sci, Inst Shanghai Inst Ceram, Shanghai 200050, Peoples R China
关键词： Photocatalysis; Zn single atoms; Porous tubular g-C3N4; Degradation of pollutants; Sterilization
期刊名称：RARE METALS （ 影响因子：11.0； 五年影响因子：8.4 ）
ISSN： 1001-0521
年卷期： 2025 年 44 卷 7 期
页码：
收录情况： SCI
摘要： High-concentration single-atom doping remains a formidable challenge due to the propensity for single atoms to form clusters or aggregate at elevated concentrations. Herein, high-concentration (10.8 wt%) Zn single-atom-doped porous tubular g-C3N4 (ZCN) was successfully obtained via a template-free, one-step calcination method, exhibiting excellent photocatalytic performance. The confinement of the pore walls suppresses the Zn atom's migration and aggregation, enhancing the Zn single-atom stability. ZCN exhibited excellent photodegradation performance against tetracycline with outstanding stability. Moreover, ZCN displayed remarkable sterilization performance, achieving a 100% inactivation of Staphylococcus aureus within 90 min of visible-light exposure. Density functional theory calculations demonstrated that the Zn single-atom sites act as pivotal photocatalytic active sites, with the presence of Zn single atoms notably augmenting charge separation efficiency. This work provides a novel approach for managing photocatalytic efficiency through enlarging single-atom doping, offering an avenue for pollutant photodegradation and sterilization.
- 相关文献
作者其他论文 更多>>
-
In-situ supramolecular self-assembly strategy to fabricate carbon-doped g-C3N4 microtubes: Efficient photocatalytic removal of antibiotics and bacterial inactivation
作者：Lei, Hua;Hu, Ruibin;Yang, Hua;Lei, Hua;Lin, Jianhan;Bian, Changhao;Guo, Fengyu;Dong, Xiaoping;Guo, Fengyu;Xiao, Xingning;Yang, Hua;Wang, Wen
关键词：Supramolecular self-assembly strategy; Visible light catalysis; Tetracycline hydrochloride degradation; Bacterial inactivation; Supramolecular self-assembly strategy; Carbon-dopped g-C3N4; Visible light catalysis; Tetracycline hydrochloride degradation; Bacterial inactivation
-
pH shifting treatment of egg yolk granules /salted ovalbumin mixed gels: Reassembled of egg yolk granules effects on heat-induced amorphous aggregates
作者：Wang, Xueying;Meng, Dekun;Wang, Jiaqi;Zhang, Huajiang;Li, Hanyu;Xu, Lina;Xia, Ning;Zhang, Nan;Xiao, Chaogeng;Rayan, Ahmed M.;Ghamry, Mohamed
关键词：Egg yolk granules; pH-shifting; Assembly; Protein unfolding; Protein gel
-
Inoculation of thermophilic bacteria from giant panda feces into cattle manure reduces gas emissions and decreases resistance gene prevalence in short-term composting
作者：Fu, Jingxia;Fu, Jingxia;Tan, Yulan;Zou, Keyi;Yu, Xiumei;Ji, Lin;Zhao, Ke;Zou, Likou;Chen, Shujuan;Tan, Yulan;Zhang, Jianmin;Xiao, Xingning;Wang, Wen
关键词：Aerobic composting; Thermophilic bacteria; Greenhouse gas; Resistance genes
-
Novel microfluidic chips integrated with smart devices for in situ detection of foodborne pathogenic bacteria
作者：Hu, Ruibin;Zheng, Qingfeng;Lin, Jianhan;Yang, Hua;Wang, Wen;Wang, Wen;Lin, Jianhan;Yang, Hua
关键词：
-
Molecule self-assembly of hydrangea-shaped hollow O, Cl -codoped graphite-phase carbon nitride microspheres for efficient N-(1,3-dimethyl butyl)-N'-phenyl-p-phenylenediamine quinone photodegradation and bacteria disinfection
作者：Chen, Xiangyu;Wu, Jianhao;Wang, Xiaozhuo;Jia, Rongrong;Li, Lan;Wang, Yixuan;Cai, Yuxing;Chen, Zhi;Jin, Cheng-Chao;Zhang, Nan;Wang, Xinquan;Qi, Peipei;Wang, Rongyan
关键词：Open porous carbon nitride microspheres; Molecule self-assembly; 6PPD-Q photodegradation; Bacteria disinfection; Treatment of antibiotic residues
-
Chlorine tolerance in foodborne pathogens: definitions, identification methods, and mechanisms
作者：Wang, Wen;Yu, Xiaoping;Wang, Wen;Yu, Xiaoping;Liu, Feng;Xiao, Xingning;Liu, Feng;Huang, Kang
关键词：
-
High-risk and virus-linked antibiotic resistome in swine farms: metagenomic profiling of cross-species transmission risks among humans, pigs, and soil
作者：Lyu, Wentao;Chen, Qu;Xiao, Xingning;Xiao, Yingping;Yang, Hua;Ma, Lingyan;Jin, Yuanxiang;Wang, Wen
关键词：Virome; ARG-carrying virus; Antibiotic resistance genes; Transmission risks; Occupational exposure
