Multi-Residue Screening of Pesticides in Aquatic Products Using High-Performance Liquid Chromatography-Tandem High-Resolution Mass Spectrometry

文献类型： 外文期刊

第一作者： Wang, Shouying

作者： Wang, Shouying;Yang, Guangxin;Tang, Yunyu;Wang, Yuan;Shen, Xiaosheng;Yu, Huijuan;Kong, Cong;Wang, Shouying;Si, Wenshuai;Zhai, Wenlei;Fodjo, Essy Kouadio

作者机构：

关键词： pesticide residues; multi-residue screening; aquatic product; high-resolution mass spectrometry; sample preparation; QuEChERS; fish; crab; crayfish

期刊名称：FOODS （ 影响因子：5.2； 五年影响因子：5.5 ）

ISSN：

年卷期： 2023 年 12 卷 6 期

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收录情况： SCI

摘要： Pesticide residues in aquatic products are of great concern due to the risk of environmental transmission and their extensive use in aquaculture. In our work, a quick screening approach was developed for the qualitative and semi-quantitative screening of 87 pesticide residues in aquatic products. The sample preparation was investigated, including extract solvent, extract methods, buffer salts, lipid removal, cleanup materials and filter membranes for aquatic products. Samples were extracted using a modified QuEChERS procedure, and two clean-up procedures were developed for UHPLC-Q/Orbitrap MS analysis based on the fat content of the aquatic products. The screening detection limits for all studied pesticides were distributed between 1 and 500 mu g/kg in the three representative matrices. Seventy-one pesticides could be analyzed with a screening limit between 1 and 25 mu g/kg in grass carp and crayfish, sixty-one pesticides could be screened for limits between 1 and 50 mu g/kg in crab. The accuracy results showed that recoveries ranged from 50 to 120% for 60, 56 and 52 pesticides at medium-level for grass carp, crayfish and crab, respectively. At high spiking levels, 74, 65 and 59 pesticides were recovered within the range of 50-120% for the three matrices, respectively. The relative standard deviations of most compounds in different matrices were less than 20%. With this method, the local farmed aquatic products were tested for pesticide residues. In these samples, ethoxyquinoline, prometryn and phoxim were frequently detected. The majority of these confirmed compounds did not exceed 2.00 mu g/kg. A grass carp with trichlorfon at 4.87 mu g/kg and two carps with ethoxyquinoline at 200 mu g/kg were detected, indicating the potential dietary risk.

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