Efficient Production of 2,5-Furandicarboxylic Acid via Chemobiocatalytic Sequential Catalysis of Bread Waste in a One-Pot, Three-Step Process Manner in a Benign Reaction System
文献类型： 外文期刊
第一作者： Liu, Xinran
作者： Liu, Xinran;He, Yucai;Liu, Xinran;He, Yucai;Ma, Cuiluan;Zheng, Mingming
作者机构：
关键词： 2,5-furandicarboxylic acid; waste bread; 5-hydroxymethylfurfural; lipase; chemoenzymatic sequential reaction
期刊名称：ACS SUSTAINABLE CHEMISTRY & ENGINEERING （ 影响因子：7.3； 五年影响因子：8.0 ）
ISSN： 2168-0485
年卷期： 2025 年 13 卷 15 期
页码：
收录情况： SCI
摘要： 2,5-Furandicarboxylic acid (FDCA) is an essential biobased dibasic acid with a structure similar to that of the petroleum-based bulk chemical terephthalic acid. In this research, a highly effectual catalytic process was acquired to transform waste bread (WB) into FDCA in a one-pot, three-step approach. First, 5-hydroxymethylfurfural (24.8 wt % yield) was acquired from WB (40 g/L) in the deep eutectic solvent (DES) choline chloride:lactic acid (ChCl:LA)-H2O (ChCl:LA, 15 wt %) medium for 15 min at 180 degrees C. The WB-derived HMF was oxidized to 2,5-furandicarboxaldehyde (97.4% yield) using Escherichia coli pRSFDuet-GOase within 5 h. Afterward, WB-derived DFF was transformed to FDCA (0.291 g of FDCA per g of WB) using immobilized lipase powder CL (CL-IM) in tert-butanol:ethyl acetate (t-BuOH:EtOAc = 1:1, v/v) at 40 degrees C for 9 h. This chemobiological route from food waste to FDCA afforded a new idea for valorization of waste into valuable biobased chemicals in a green and effectual way.
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