Degradation of Kresoxim-Methyl in Different Soils: Kinetics, Identification of Transformation Products, and Pathways Using High-Resolution-Mass-Spectrometry-Based Suspect and Non-Target Screening Approaches

文献类型： 外文期刊

第一作者： Man, Yanli

作者： Man, Yanli;Wang, Wei;Mao, Liangang;Zhu, Lizhen;Zhang, Yanning;Zhang, Lan;Jiang, Hongyun;Liu, Xingang

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关键词： kresoxim-methyl; soil; transformation product; HRMS; toxicity

期刊名称：JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY （ 影响因子：5.895； 五年影响因子：6.048 ）

ISSN： 0021-8561

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收录情况： SCI

摘要： This study investigated the degradation of strobilurin fungicide kresoxim-methyl (KM) in three typical agricultural soils from China by aerobic and anaerobic degradation experiments, focusing on degradation kinetics of KM, identification of transformation products (TPs), and prediction of toxicity end points via in silico approaches. KM showed a pronounced biphasic degradation in different soils and could rapidly degrade, with DT50 of <3 days. Four TPs were identified by high-resolution mass spectrometry (HRMS), and three of them have never been reported before. Possible degradation pathways of KM in soil were proposed, including hydrolysis, oxidation, and reduction, and the main mechanism involved in the biodegradation of KM was the hydrolysis of methyl ester regardless of aerobic or anaerobic conditions. The results of toxicity evaluation indicated that some TPs are more toxic than KM and may have a developmental toxicity and mutagenicity, and further risk assessment should be carried out.

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