Accurate assembly of ferrocene-functionalized {Ti(22)Fc(4)} clusters with photocatalytic amine oxidation activity

文献类型： 外文期刊

第一作者： Han, Er-Meng

作者： Han, Er-Meng;Yi, Xiao-Yi;Yan, Jun;Liu, Chao;Yu, Wei-Dong;Li, Lei-Jiao

作者机构：

期刊名称：CHEMICAL COMMUNICATIONS （ 影响因子：5.996； 五年影响因子：5.818 ）

ISSN： 1359-7345

年卷期： 2021 年 57 卷 22 期

页码：

收录情况： SCI

摘要： We report here the synthesis of a ferrocene-functionalized {Ti(22)Fc(4)} cluster with a 'dimer-of-clusters' topology, which represents the largest Ti-oxo cluster (TOC) modified with organometallic groups ever reported. The exact assembly path of {Ti(22)Fc(4)} can be inferred from its two substructures, {Ti(11)Fc(2)} and {Ti(5)Fc}, which can also be synthesized independently through subtle changes in reaction conditions. Furthermore, we used these clusters as photocatalysts, and have studied, for the first time, the photocatalytic activity of TOCs in the oxidative coupling of amines.

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