Solvent issues in the Baylis-Hillman reaction of 5-hydroxymethyl furfural (HMF) and 5-glucosyloxymethyl furfural (GMF). Towards no-solvent conditions
文献类型： 外文期刊
第一作者： Wang, Lianjie
作者： Wang, Lianjie;Tan, Jia-Neng;Ahmar, Mohammed;Queneau, Yves;Tan, Jia-Neng
作者机构：
关键词： carbohydrate; GMF; HMF; ICS-29; Morita-Baylis-Hillman reaction; no-solvent
期刊名称：PURE AND APPLIED CHEMISTRY （ 影响因子：2.453； 五年影响因子：5.672 ）
ISSN： 0033-4545
年卷期： 2019 年 91 卷 7 期
页码：
收录情况： SCI
摘要： The possibility to apply solventless conditions for the Baylis-Hillman reaction of 5-hydroxymethyl furfural (HMF) and its glucosylated analog, glucosyloxymethyl furfural (GMF) has been investigated. This study shows that highly functionalized adducts can be obtained in fair to good yields, under the conditions combining the renewability of the substrates, the straightforwardness of the strategy, and the lowered cost and toxicity of the solvent conditions. The issue of the polarity of the furanic substrate is addressed by comparing HMF with furfural and GMF.
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