Effects of crosslinked elastomer particles on heterogeneous nucleation of isotactic PP in dynamically vulcanized EPDM/PP and EOC/PP blends

文献类型： 外文期刊

第一作者： Uthaipan, Nattapon

作者： Uthaipan, Nattapon;Thitithammawong, Anoma;Jarnthong, Methakarn;Peng, Zheng;Junhasavasdikul, Banja;Nakason, Charoen

作者机构：

关键词： Polypropylene;Thermoplastic vulcanizates;Isothermal crystallization;Crystallization characteristics;Nucleation

期刊名称：JOURNAL OF POLYMER RESEARCH （ 影响因子：3.097； 五年影响因子：2.599 ）

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收录情况： SCI

摘要： The isothermal and non-isothermal crystallizations of PP in neat form and in the TPVs EPDM/PP and EOC/PP were investigated using differential scanning calorimetry (DSC). The crystallization of PP was systematically studied by fitting mathematical models, and was later confirmed by X-ray diffraction (XRD) and by scanning electron microscopy (SEM). The experiments revealed that crosslinked elastomer particles first accelerated the primary nucleation of the PP matrix, acting effectively as a nucleating agent that reduces the induction time while increasing the nucleation efficiency. In the secondary nucleation regime (growth of spherulites), the crosslinked elastomer particles enhanced crystal growth rate, reducing the nucleation energy contribution from PP chain folding. Moreover, the crosslinked elastomer particles increased the final thickness of PP lamellae from that of neat PP, and this was corroborated by the XRD results. On comparing the two types of elastomer, it was found that the EOC particles were more effective in heterogeneous cell nucleation than the EPDM particles. The morphological study by SEM revealed completely altered PP spherulite size and shape, as well as their altered distribution, affected by heterogeneous nucleation effects of the crosslinked elastomer particles.

分类号： O6

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