文献类型： 外文期刊
第一作者： Qin, SH
作者： Qin, SH;Qiu, KY;Swift, G;Wu, SG;Westmoreland, DG
作者机构：
关键词： 'living' radical polymerization;thermal iniferter;diethyl 2,3-dicyano-2,3-diphenylsuccinate (DCDPS);styrene;block copolymer
期刊名称：POLYMER INTERNATIONAL （ 影响因子：2.99； 五年影响因子：2.74 ）
ISSN： 0959-8103
年卷期： 2001 年 50 卷 3 期
页码：
收录情况： SCI
摘要： The bulk polymerization of styrene (St) initiated with a hexa-substituted-ethane type initiator, diethyl 2,3-dicyano-2,3-diphenylsuccinate (DCDPS), was investigated. It was found that DCDPS served as a thermal iniferter for polymerization of St and the polymerization had some characteristics in common with living radical polymerization, ie, both the yield and the molecular weight of the resulting polymers increased with increasing reaction time. The resultant polystyrene can act as a macroinitiator for chain-extension polymerization of St or for radical polymerization of methyl methacrylate to give a block copolymer. (C) 2001 Society of Chemical Industry.
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