Palladium-catalyzed [3+2] cycloaddition of 4-vinyl-4-butyrolactones with sulfamate-derived cyclic imines: construction of sulfamate-fused pyrrolidines

文献类型: 外文期刊

第一作者: Sun, Honghao

作者: Sun, Honghao;Ding, Siyuan;Huang, Jiaxing;Guo, Hongchao;Sun, Honghao;Ding, Siyuan;Huang, Jiaxing;Guo, Hongchao;Sun, Honghao;Wang, Bo

作者机构:

期刊名称:ORGANIC & BIOMOLECULAR CHEMISTRY ( 影响因子:2.7; 五年影响因子:2.9 )

ISSN: 1477-0520

年卷期: 2024 年 23 卷 1 期

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收录情况: SCI

摘要: The palladium-catalyzed [3 + 2] decarboxylative cycloaddition of 4-vinyl-4-butyrolactones with sulfamate-derived cyclic imines has been developed, providing the sulfamate-fused pyrrolidine derivatives in high yields with good diastereoselectivities. The scale-up reaction and further derivation of the product worked well, demonstrating the potential application of the current reaction in organic synthesis. A plausible reaction mechanism was also proposed.

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