文献类型： 外文期刊

作者： Zhou, Jin ¹ ; Gao, Wenfang ¹ ; Xie, Lina ¹ ; Zhang, Ruju ³ ; Zhang, Yunxian ⁴ ; Wei, Zimin ¹ ;

作者机构： 1.Tianjin Normal Univ, Coll Life Sci, Tianjin Key Lab Anim & Plant Resistance, Tianjin 300387, Peoples R China

2.Northeast Agr Univ, Coll Life Sci, Harbin 150030, Peoples R China

3.Jiangsu Acad Agr Sci, Inst Anim Sci, Nanjing 210014, Peoples R China

4.Beijing Normal Univ, Coll Environm, Beijing 100091, Peoples R China

关键词： Catechol; Pyrogallol; Glycine; Humification; Humic acid

期刊名称：BIORESOURCE TECHNOLOGY （ 影响因子：9.7； 五年影响因子：9.4 ）

ISSN： 0960-8524

年卷期： 2024 年 403 卷

页码：

收录情况： SCI

摘要： Humus is the stable form of carbon storage in straw compost. The phenol-amine reaction is a pathway for humus formation in straw compost. In this study, two reaction systems, GP group (pyrogallol and glycine) and GCP group (catechol, pyrogallol, and glycine), were constructed in a simulated composting environment and revealed the molecular binding mechanism of the phenol-amine reaction through spectroscopy and mass spectrometry. The results showed that phenolic self-polymerization was faster than phenol-amine reaction. Therefore, the aromatization degree of GP was 27.14 % higher than that of GCP. The phenol-amine reaction first produced fulvic acid, and then formed humus units rich in active functional group structures (i.e., phenolic hydroxyl and carboxyl groups). These units further captured small molecule compounds to form humic acid eventually. This study would provide theoretical support for exploring the humus formation process and the promotion of straw humification by adding phenol or amino acids to compost.