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Synthesis of carbon nitride in-situ coupled tungsten oxide heterojunction with efficient photocatalytic redox properties

文献类型： 外文期刊

作者： Yang, Hui 1 ; Wang, Xiaowei 1 ; Habib, Haris 2 ; Fan, Siyu 4 ; Rehman, Zia Ur 1 ; Liu, Yuxue 5 ; Wang, Yue 4 ; Lin, Hui 5 ; Wang, Xiaozhi 1 ; Hou, Jianhua 1 ;

作者机构： 1.Yangzhou Univ, Coll Environm Sci & Engn, Yangzhou 225127, Peoples R China

2.Yanshan Univ, Sch Sci, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China

3.Yanshan Univ, Sch Sci, Key Lab Microstruct Mat Phys Hebei Prov, Qinhuangdao 066004, Peoples R China

4.Kyushu Inst Technol, Fac Engn, Dept Appl Chem, Kitakyushu 8048550, Japan

5.Zhejiang Acad Agr Sci, Inst Environm Resource Soil & Fertilizer, State Key Lab Managing Biot & Chem Threats Qual &, Hangzhou 310021, Peoples R China

关键词： In-situ coupled; Transfer of electrons; Oxygen vacancies; Photoredox properties

期刊名称：RENEWABLE ENERGY （ 影响因子：9.1； 五年影响因子：8.3 ）

ISSN： 0960-1481

年卷期： 2025 年 245 卷

页码：

收录情况： SCI

摘要： Herein, a heterogeneous photocatalyst of carbon nitride (CN) in-situ coupled tungsten oxide (WO3) were successfully prepared, which obtained by a one-step calcination treatment. The growth of WO3 nanorods on CN nanosheets increased the specific surface area and pore abundance of the material, resulting in the enhancement of the visible light absorption range of CN. The existence of oxygen vacancies in heterojunction can drive the transfer efficiency of photogenerated electrons from CN to WO3, which provides the effective separation of photogenerated carriers and in turn improves photocatalytic activity. The photocatalytic hydrogen production rate of CN-0.3 (in which 0.3 represents the addition amount of WCl6) was as high as 5.58 mmol/g/h, which reached 6.6-times higher than that of CN (0.85 mmol/g/h). In addition, the photocatalytic activity of CN-0.3 was still retained 81 % after five experiments of hydrogen production, indicating its stability and recyclability. Meanwhile, CN-0.3 has the highest photocatalytic reaction rate constant of 0.020 min-1 for degrading dye pollution at about 10-times higher rate compared with CN (0.002 min-1) and about 20-times higher than that of WO3 (0.001 min-1). CN-0.3 also has some degradation effect on antibiotics of TC and CIP, which improves the universality of photocatalyst in wastewater treatment. This work aims to offer viable and significant approaches for designing CN-based photocatalysts, hence enabling their efficient application in many photocatalytic domains.

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