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In situ formation of Ca(OH)(2) coating shell to extend the longevity of zero-valent iron biochar composite derived from Fe-rich sludge for aqueous phosphorus removal

文献类型： 外文期刊

作者： Zhang, Qi 1 ; Li, Jun 1 ; Chen, De 2 ; Xiao, Wendan 2 ; Zhao, Shouping 2 ; Ye, Xuezhu 2 ; Li, Hui 5 ;

作者机构： 1.Zhejiang Univ Technol, Coll Environm, Hangzhou 310014, Peoples R China

2.Zhejiang Acad Agr Sci, State Key Lab Managing Biot & Chem Threats Qual, 298 Desheng Middle Rd, Hangzhou 310021, Peoples R China

3.Zhejiang Acad Agr Sci, Key Lab Informat Traceabil Agr Prod, 298 Desheng Middle Rd, Hangzhou 310021, Peoples R China

4.Zhejiang Acad Agr Sci, Inst Agroprod Safety & Nutr, 298 Desheng Middle Rd, Hangzhou 310021, Peoples R China

5.Hunan Acad Forestry, Changsha 410004, Peoples R China

6.State Key Lab Utilizat Woody Oil Resource, Changsha 410004, Peoples R China

关键词： Zero valent iron biochar composite; Fe/C micro-electrolysis; Ca(OH)(2) coating shell; phosphorus removal; longevity

期刊名称：SCIENCE OF THE TOTAL ENVIRONMENT （ 影响因子：10.753； 五年影响因子：10.237 ）

ISSN： 0048-9697

年卷期： 2023 年 854 卷

页码：

收录情况： SCI

摘要： Despite being an effective and attractive functional strategy for aqueous phosphorus (P) removal, the use of zero valent iron (ZVI) biochar composites has been severely impeded by rapid self-erosion. We describe a new approach for extending the lifespan of Fe-rich sludge-derived ZVI biochar composites via CaCl2 modification. Preliminary results showed that composites obtained at 900 degrees C without modification (MBC900) and at 900 degrees C with 100 g Cl/kg addition (MBC900(100)) had the highest P removal efficiency. In subsequent batch experiments, MBC900(100) exhibited more stable P adsorption capacities than MBC900 over a wide pH range (4-10) and at various dosages, which was enhanced by the presence of HCO3-. The theoretical maximum P adsorption capacities of MBC900 and MBC900(100) were 227.14 and 224.15 mg g(-1), respectively. Kinetic analysis indicated that chemisorption dominated the removal process. Continuous experimental data using the Yoon-Nelson model indicated that MBC900(100) had a considerably longer half-penetration time. The primary mechanism of P removal by MBC900 was Fe/C micro-electrolysis. As the embedded CaO formed a dissolvable Ca(OH)(2) shell in situ on the surface of MBC900(100), the phosphate formed a precipitate with free Ca2+ before being removed via micro-electrolysis. Overall, CaCl2 modification successfully enhanced the longevity of the ZVI biochar composites.

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