Microwave-Enabled Fast Preparation of a Metal-Organic Framework Hybrid Membrane for Filtration-Enhanced Simultaneous Separation and Detection of Aflatoxin B1
文献类型: 外文期刊
作者: Ma, Tongtong 1 ; Zhang, Qi 1 ; Yuan, Lei 1 ; Li, Zhishang 1 ; Zhang, Lin 1 ; Zhang, Jie 1 ; Yan, Shugang 1 ; Xu, Xiahong 2 ; Ying, Yibin 1 ; Fu, Yingchun 1 ;
作者机构: 1.Zhejiang Univ, Coll Biosyst Engn & Food Sci, Key Lab Intelligent Equipment & Robot Agr Zhejiang, Hangzhou 310058, Peoples R China
2.Zhejiang Acad Agr Sci, Inst Agroprod Safety & Nutr, State Key Lab Managing Biot & Chem Threats Qual &, Hangzhou 310021, Peoples R China
关键词: metal-organic framework; hybrid membrane; fluorescence sensor; filtration; mycotoxins
期刊名称:ACS APPLIED MATERIALS & INTERFACES ( 影响因子:9.5; 五年影响因子:9.6 )
ISSN: 1944-8244
年卷期: 2024 年 16 卷 19 期
页码:
收录情况: SCI
摘要: Mycotoxin contamination in food and the environment seriously harms human health. Sensitive and timely detection of mycotoxins is crucial. Here, we report a dual-functional hybrid membrane with absorptivity and responsiveness for fluorescent-quantitative detection of mycotoxin aflatoxin B1 (AFB1). A biomineralization-inspired and microwave-accelerated fabrication method was established to prepare a hybrid membrane with a metal-organic framework (MOF) loaded in high density. The MOF presented high efficiency in capturing AFB1 and showed fluorescence intensity alteration simultaneously, enabling a dual adsorption-response mode. Deriving from the inherent porous structure of the hybrid membrane and the absorptive/responsive ability of the loaded MOF, a filtration-enhanced detection mode was elaborated to provide a 1.67-fold signal increase compared with the conventional soaking method. Therefore, the hybrid membrane exhibited a rapid response time of 10 min and a low detection limit of 0.757 ng mL(-1), superior to most analogues in rapidity and sensitivity. The hybrid membrane also presented superior specificity, reproducibility, and anti-interference ability and even performed well in extreme environments such as strong acid or alkaline, satisfying the practical requirements for facile and in-field detection. Therefore, the membrane had strong applicability in chicken feed samples, with a detection recovery between 70.6% and 101%. The hybrid membrane should have significant prospects in the rapid and in-field inspection of mycotoxins for agriculture and food.
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