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A novel molecularly imprinted polymer composite based on polyaniline nanoparticles as sensitive sensors for parathion detection in the field

文献类型： 外文期刊

作者： Liang, Ying 1 ; Wang, Hongmei 2 ; Xu, Yixin 1 ; Pan, Hongzhi 4 ; Guo, Keyu 1 ; Zhang, Ying 1 ; Chen, Yaqiong 1 ; Liu, Dezhi 1 ; Zhang, Yu 1 ; Yao, Chunxia 2 ; Yu, Yanyan 5 ; Shi, Guoyue 6 ;

作者机构： 1.Shanghai Univ Med & Hlth Sci, Sch Pharm, Shanghai 201318, Peoples R China

2.Shanghai Acad Agr Sci, Shanghai Serv Platform Agro Prod Qual & Safety Ev, Engn Res Ctr Agro Prod Qual & Safety, Inst Agro Food Stand & Testing Technol,Shanghai, Shanghai 201403, Peoples R China

3.Shanghai Ocean Univ, Coll Marine Ecol & Environm, Shanghai 201306, Peoples R China

4.Shanghai Univ Med & Hlth Sci, Sci & Technol Dept, Shanghai 201318, Peoples R China

5.Xuzhou Med Univ, Jiangsu Key Lab New Drug Res & Clin Pharm, Xuzhou 221004, Jiangsu, Peoples R China

6.East China Normal Univ, Dept Chem, 500 Dongchuan Rd, Shanghai 200241, Peoples R China

关键词： Polyaniline nanoparticles; Molecularly imprinted polymers; Parathion; Electrochemical detection

期刊名称：FOOD CONTROL （ 影响因子：6.652； 五年影响因子：6.498 ）

ISSN： 0956-7135

年卷期： 2022 年 133 卷

页码：

收录情况： SCI

摘要： This paper presents a novel strategy for the real-time detection of organophosphate pesticides by imprinting parathion molecules at the surface of conductive functional polyaniline nanoparticles (PANIs). It has been demonstrated that the introduction of vinyl group on the surface of PANIs is not only beneficial to the selectivity of imprinting polymerization, but also to the preconcentration of parathion template into the polymer by charge attraction between the template and the functionalized PANIs. Through the above two effects, parathion imprinted polymer was successfully prepared on the surface of PANIs. When the novel material was used to detect parathion in vegetable samples, its selectivity coefficient was observed to be nearly ten times than that of its non-imprinted counterpart. It also possessed high selectivity toward parathion in comparison to structurally similar pesticide compounds. There was a linear relationship between the reductive peak current and parathion concentrations from testing concentrations ranging from between 3.40 x 10(-8) M to 1.87 x 10(-5) M with a detection limit of 1.13 x 10(-8) M (S/N = 3). These results indicate that the newly developed sensor is highly effective for the detection of parathion, and establish the potential of the molecular imprinting approach for future analysis of other organophosphate pesticides.

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